Grimmite

NiCo2S4
IMA status
  • Approved
IMA symbol
Gmm
IMA approved
2020
Also known as
  • Grimmiet
  • IMA2020-060

Where it forms, where it's found

Geological setting

In in siderite–sphalerite gangue in a uranium and base metal deposit.

Type locality
Uranium Mine No. 9 (Shaft No. 9)
  1. Háje
  2. Příbram District
  3. Central Bohemian Region
  4. Czech Republic

49.6700°, 14.0323°

12recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Grey with a pinkish tint
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
4.96 g/cm³

Optical

Pleochroism
Not Visible
Optical colour
Creamy grey with a pinkish tint
Internal reflections
None
Tropism
Isotropic
Reflectance R%
(38.6) 400, (41.1) 440, (42.5) 470, (43.7) 500, (45.9) 546, (46.5) 560, (47.7) 589, (48.9) 620, (50.2) 650, (51.3) 680, (51.9) 700
Reflected-light panel
46.2 %isotropic · single curve
Specimen sRGB 247, 167, 86
White reference100 % reflector under same lamp
Reflected colour
Creamy grey with a pinkish tint
Internal reflections
None

Crystallography

Crystal system
Isometric
Space group
#222
Cell parameters
a = 9.3933(9) Å
Unit cell volume
828.81 ų
Z
8
Type-locality form

Rare idiomorphic to hypidiomorphic grains up to 200 × 70 µm in size or veinlet aggregates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
16SSulfurSulfur432.060128.240
42.07%
27CoCobaltCobalt258.933117.866
38.67%
28NiNickelNickel158.69358.693
19.26%
Total304.799100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Grimmiet
  • IMA2020-060

In other languages

German
Grimmit · IMA 2020-060
Italian
Grimmite

Classification

Strunz
10th ed.

2.DA

  • 2Sulfides and SulfosaltsClass
  • 2.DMetal Sulfides, M: S = 3 :4 and 2:3Division
  • 2.DAM:S = 3:4Group
  • 2.DAGrimmiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1956Lotgering, F.K. (1956) Ferrimagnetism of sulfides and oxides. III. Oxygen and sulfur spinels containing cobalt (MCo2O4 and MCo2S4). Philips Research Reports: 11: 337-350.
  2. 1968Knop, Osvald, Reid, K. I. G., Sutarno, Nakagawa, Yasuaki (1968) Chalkogenides of the transition elements. VI. X-Ray, neutron, and magnetic investigation of the spinels Co3O4, NiCo2O4, Co3S4, and NiCo2S4. Canadian Journal of Chemistry, 46 (22). 3463-3476 doi:10.1139/v68-576DOI: 10.1139/v68-576
  3. 1976Mincheva-Stefanova, J., Kostov, I. (1976) Siegenite and the "miscibility" between linnaeite and polydymite. Geokhimiya, Mineralogiya i Petrologiya: 4: 35-56.
  4. 1991Kesler, A.Ya., Smirnov, S.G., Pokholok, K.V., Viting, B.N. (1991) Electronic structure of cobalt-nickel thio-spinels. Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy: 27(6): 1162-1165 (in Russian).
  5. 2015Xia, Chuan, Li, Peng, Gandi, Appala Naidu, Schwingenschlögl, Udo, Alshareef, Husam N. (2015) Is NiCo2S4 Really a Semiconductor? Chemistry of Materials, 27. 6482-6485 doi:10.1021/acs.chemmater.5b01843DOI: 10.1021/acs.chemmater.5b01843
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Grimmite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/grimmite-55244},
  note      = {Accessed 2026-05-11}
}