Polydymite

Ni2+Ni3+2S4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pld
Discovered
1876
Also known as
  • Grünauite
  • Polydymiet
  • Polydymita
  • +2 more

Where it forms, where it's found

Type locality
Grüneau Mine (Grüne Au Mine
  1. Grünau Mine)
  2. Schutzbach
  3. Daaden-Herdorf
  4. Altenkirchen
  5. Rhineland-Palatinate
  6. Germany

50.7536°, 7.8984°

154recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Colour
Violet gray · copper red · light gray · or steel gray
Streak
Black gray
Cleavage

Indistinct

Optical

Optical type
Isotropic
Reflectance R%
(44.3) 400, (45.3) 440, (46.0) 480, (46.2) 520, (45.8) 560, (46.2) 600, (48.0) 640, (51.2) 680, (53.0) 700
Reflected-light panel
47.3 %isotropic · single curve
Specimen sRGB 242, 167, 92
White reference100 % reflector under same lamp

Crystallography

Crystal system
Isometric
Space group
#222
Cell parameters
a = 9.405 Å
Z
8
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
28NiNickelNickel358.693176.079
57.86%
16SSulfurSulfur432.060128.240
42.14%
Total304.319100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Co

Synonyms

  • Grünauite
  • Polydymiet
  • Polydymita
  • Sainit
  • Saynit

In other languages

French
Polydymite
German
Polydymit · Trinickeltetrasulfid
Italian
polidimite · polydymite
Chinese
輝鎳礦

Classification

Strunz
10th ed.

2.DA.05

  • 2Sulfides and SulfosaltsClass
  • 2.DMetal Sulfides, M: S = 3 :4 and 2:3Division
  • 2.DAM:S = 3:4Group
  • 2.DA.05PolydymiteSpecies
Dana
8th ed.

02.10.01.07

  • 02SulfidesClass
  • 02.10AmBnXp, with (m+n):p = 3:4Type
  • 02.10.01Linnaeite Group (Isometric: Fd3m)Group
  • 02.10.01.07PolydymiteSpecies
CIM

3.11.4

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.11Sulphides etc. of NiGroup
  • 3.11.4PolydymiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1876Laspeyres, H. (1876) Chemische Untersuchungen von Nickelerzen; 1. Polydymit, ein neues Nickelerz. Journal für Praktische Chemie: 122: 397-413.
  2. 1916Zambonini (1916): Riv. min.: 47.
  3. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  4. 1947Lundqvist, D. (1947) X-ray studies on the binary system Ni-S. Arkiv för Kemi, Mineralogi och Geologi: 24A(21): 1-12.
  5. 1953Gritsaenko, G.S., Sludskaya, N.N., Aidinyan, N.K. (1953) Synthesis of vaesite and polydymite: Zapiski Vsesoyus. Mineralog. Obshchestva: 82: 42-52.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Polydymite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/polydymite-3258},
  note      = {Accessed 2026-05-11}
}