Gunterite

Na4Ca[V10O28] · 20H2O
IMA status
  • Approved
IMA symbol
Gun
IMA approved
2011
Also known as
  • Gunteriet
  • IMA2011-001

Where it forms, where it's found

Geological setting

Efflorescences on the sandstone walls of the mine workings and in fractures in the sandstone forming from the oxidation of montroseite–corvusite assemblages.

Type locality
West Sunday Mine
  1. Slick Rock Mining District
  2. Colorado
  3. USA

38.0800°, -108.8217°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Orange-yellow
Streak
Yellow
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
2.398 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 78°
Refractive index
1.735 – 1.825
Surface relief
High
Principal indices
nα 1.735 · nβ 1.770 · nγ 1.825
Pleochroism
Visible

X = yellow; Y = orange; Z yellow.

Dispersion
v < r, strong, parallel
Extinction
X = b, Y ≈ c.
UV response
Not fluorescent.
Notes

γ calculated (index fluids decomposed mineral) Absorption: Y > X > Z.

Michel-Lévy diagramhighlighted lineδ = 0.0900
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]900 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation900 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 19.848(2) Å · b = 10.1889(11) Å · c = 13.1184(15) Å
Cell angles
β = 130.187(9) °
Ratio a:b:c
1 : 0.513 : 0.661
Z
2
Parting
none
Type-locality form

Tabular on (001) and generally stacked into elongate curved multiple crystals up to 0.5 mm in maximum dimension. The crystals typically exhibit warping and, in some cases, skeletal growth features.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4815.999767.952
52.97%
23VVanadiumVanadium1050.942509.420
35.14%
11NaSodiumSodium422.99091.960
6.34%
1HHydrogenHydrogen401.00840.320
2.78%
20CaCalciumCalcium140.07840.078
2.77%
Total1449.730100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Gunteriet
  • IMA2011-001

In other languages

German
Gunterit · IMA 2011-001
Italian
gunterite

Classification

Strunz
10th ed.

4.HC.35

  • 4OxidesClass
  • 4.HV[5,6] VanadatesDivision
  • 4.HC[6]-SorovanadatesGroup
  • 4.HC.35GunteriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2011www.uidaho.edu (2011) http://www.uidaho.edu/sci/geology/newsandevents/geologynews/gunterite
  2. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011. CNMNC Newsletter No 9. Mineralogical Magazine, 75 (4) 2535-2540 doi:10.1180/minmag.2011.075.4.2535 DOI: 10.1180/minmag.2011.075.4.2535
  3. 2011Kampf, A. R., Hughes, J. M., Marty, J., Nash, B. (2011) Gunterite, Na4(H2O)16(H2V10O28)·6H2O, a new mineral species with a doubly-protonated decavanadate polyanion: crystal structure and descriptive mineralogy. The Canadian Mineralogist, 49 (5) 1243-1251 doi:10.3749/canmin.49.5.1243 DOI: 10.3749/canmin.49.5.1243
  4. 2013(2013) Gunterite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2021Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2021) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 61. European Journal of Mineralogy, 33 (3) 299-304 doi:10.5194/ejm-33-299-2021 DOI: 10.5194/ejm-33-299-2021
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Gunterite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/gunterite-42440},
  note      = {Accessed 2026-05-11}
}