Protocaseyite

[Al4(OH)6(H2O)12][V10O28] · 8H2O
IMA status
  • Approved
IMA symbol
Pcy
IMA approved
2021
Also known as
  • IMA2020-090
  • Protocaseyiet

Where it forms, where it's found

Geological setting

Part of a low-temperature, post-mining, secondary mineral assemblage.

Type locality
Burro Mine
  1. San Miguel County
  2. Colorado
  3. USA

38.0451°, -108.8896°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Saffron yellow
Streak
Orange yellow
Tenacity
brittle
Cleavage
Very Good

Two very good cleavages. One on (111) and one along the length of the blades and at an angle to the (111) face - possibly on (010).

curved

Fracture
Sub-Conchoidal
Density
2.45 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.755 – 1.8
Surface relief
High
Principal indices
nα 1.755 · nβ 1.80 · nγ 1.80
Pleochroism
Visible

X = Y = yellow; Z = orange.

Dispersion
Extreme.
UV response
None
Notes

Absorption: X ≈ Y < Z.

Michel-Lévy diagramhighlighted lineδ = 0.0450
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]450 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation450 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 9.435(2) Å · b = 10.742(3) Å · c = 11.205(3) Å
Cell angles
α = 75.395(7) ° · β = 71.057(10) ° · γ = 81.286(6) °
Ratio a:b:c
1 : 1.139 : 1.188
Z
1
Type-locality form

Thick blades.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5415.999863.946
56.55%
23VVanadiumVanadium1050.942509.420
33.35%
13AlAluminiumAluminium426.982107.928
7.06%
1HHydrogenHydrogen461.00846.368
3.04%
Total1527.662100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2020-090
  • Protocaseyiet

In other languages

German
IMA 2020-090 · Protocaseyit

Classification

Strunz
10th ed.

4.HC

  • 4OxidesClass
  • 4.HV[5,6] VanadatesDivision
  • 4.HC[6]-SorovanadatesGroup
  • 4.HCProtocaseyiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2021Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2021) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) CNMNC Newsletter No 60. Mineralogical Magazine, 1-5 doi:10.1180/mgm.2021.30DOI: 10.1180/mgm.2021.30
  2. 2022(2022) Protocaseyite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2022Kampf, Anthony R., Cooper, Mark A., Hughes, John M., Ma, Chi, Casey, William H., Hawthorne, Frank C., Marty, Joe (2022) Protocaseyite, a new decavanadate mineral containing a [Al4(OH)6(H2O)12]6+ linear tetramer, a novel isopolycation. American Mineralogist, 107 (6) 1181-1189 doi:10.2138/am-2022-8059DOI: 10.2138/am-2022-8059
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Protocaseyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/protocaseyite-55381},
  note      = {Accessed 2026-05-11}
}