Hillite

Ca2Zn(PO4)2 · 2H2O
IMA status
  • Approved
IMA symbol
Hi
Discovered
1973
IMA approved
2003
Also known as
  • Hilliet
  • IMA2003-005

Where it forms, where it's found

Geological setting

Occurs in a small “gossanous” mass covering unmetamorphosed, poorly sorted argillaceous siltstones of Lower Cambrian age.

Type locality
Reaphook Hill
  1. Martins Well (Martins Well Station)
  2. Pastoral Unincorporated Area
  3. South Australia
  4. Australia

-31.3942°, 139.2983°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless to greenish grey
Streak
White
Cleavage
Perfect

on (010) and (001)

Density
3.16 g/cm³

Optical

UV response
Weak, greenish yellow fluorescence in short-wave UV light.

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.736 Å · b = 6.767 Å · c = 5.462 Å
Cell angles
α = 97.41 ° · β = 108.59 ° · γ = 107.19 °
Ratio a:b:c
1 : 1.180 : 0.952
Type-locality form

Minute tabular crystals to 0.05 mm and wedge-shaped tabular aggregates to 0.2 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
43.06%
20CaCalciumCalcium240.07880.156
21.58%
30ZnZincZinc165.38065.380
17.60%
15PPhosphorusPhosphorus230.97461.948
16.67%
1HHydrogenHydrogen41.0084.032
1.09%
Total371.506100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hilliet
  • IMA2003-005

In other languages

German
Hillit · IMA 2003-005
Italian
Hillite
Chinese
水磷锌钙石

Classification

Strunz
10th ed.

8.CG.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CGWith large and medium-sized cations, RO4:H2O = 1:1Group
  • 8.CG.05HilliteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1973Hill, R. J.; Johnson, J. E.; Jones, J. B. (1973) Scholzite and other phosphate minerals from Reaphook Hill, South Australia. Neues Jahrbuch für Mineralogie - Monatshefte, 1973 (1). 1-8 doi:10.1127/njmm/1973/1973/1DOI: 10.1127/njmm/1973/1973/1
  2. 1974Hill, R. J., Milnes, A. R. (1974) Phosphate minerals from Reaphook Hill, Flinders Ranges, South Australia. Mineralogical Magazine, 39 (306) 684-695 doi:10.1180/minmag.1974.039.306.06 DOI: 10.1180/minmag.1974.039.306.06
  3. 2003Yakubovich, O. V., Massa, W., Liferovich, R. P., Gavrilenko, P. G., Bogdanova, A. N., Tuisku, P. (2003) Hillite, a new member of the fairfieldite group: its description and crystal structure. The Canadian Mineralogist, 41 (4) 981-988 doi:10.2113/gscanmin.41.4.981 DOI: 10.2113/gscanmin.41.4.981
  4. 2004Jambor, J.L., Roberts, A.C. (2004) New mineral names. American Mineralogist: 89: 467-471.
  5. 2004Mandarino, Joseph A. (2004) New minerals. The Canadian Mineralogist, 42 (3) 921-945 doi:10.2113/gscanmin.42.3.921 DOI: 10.2113/gscanmin.42.3.921
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hillite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hillite-25585},
  note      = {Accessed 2026-05-11}
}