Kirkiite

Pb10Bi3As3S19
IMA status
  • Approved
IMA symbol
Krk
Discovered
1985
Also known as
  • IMA1984-030
  • Kirkiiet

Where it forms, where it's found

Geological setting

Pb-Zn deposit.

Type locality
Agios Philippos Mine
  1. Alexandroupoli
  2. Evros
  3. Eastern Macedonia and Thrace
  4. Greece

41.0188°, 25.8193°

4recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Steel-gray
Density
6.82 g/cm³

Optical

Optical colour
White
Anisotropism
Weak
Bireflectance
Very weak
Tropism
Anisotropic
Reflectance R%
(45.3,40.2) 420, (45.2,40.9) 460, (44.5,40.4) 500, (43.5,39.4) 540, (42.6,38.6) 580, (42.1,38.0) 620, (41.5,37.5) 660, (40.9,36.9) 700, (39.9,35.7) 740
Reflected-light panel
42.8 %anisotropic · dual curve
Specimen sRGB 230, 163, 93
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Very weak
Anisotropism
Weak
Reflected colour
White

Crystallography

Crystal system
Monoclinic
Space group
#15
Cell parameters
a = 8.700(2) Å · b = 26.237(6) Å · c = 8.774(3) Å
Cell angles
β = 119.653(4) °
Ratio a:b:c
1 : 3.016 : 1.009
Unit cell volume
1740.2 ų
Twinning

Polysynthetic

Type-locality form

Subhedral grains to 200 μm.

Comment

Data from Pinto et al. (2006) for a sample with a composition very close to the endmember.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead10207.2002072.000
58.65%
83BiBismuthBismuth3208.980626.940
17.75%
16SSulfurSulfur1932.060609.140
17.24%
33AsArsenicArsenic374.922224.766
6.36%
Total3532.846100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Sb

Synonyms

  • IMA1984-030
  • Kirkiiet

In other languages

German
IMA 1984-030 · Kirkiit
Italian
Kirkiite

Classification

Strunz
10th ed.

2.JB.30b

  • 2Sulfides and SulfosaltsClass
  • 2.JSulfosalts of PbS archetypeDivision
  • 2.JBGalena derivatives, with PbGroup
  • 2.JB.30bKirkiiteSpecies
Dana
8th ed.

03.04.17.01

  • 03SulfosaltsClass
  • 03.04ø = 3Type
  • 03.04.17— unnamed intermediate level —Group
  • 03.04.17.01KirkiiteSpecies
CIM

5.6.32

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.6Sulpharsenites etc. of Pb aloneGroup
  • 5.6.32KirkiiteSpecies

Group, growth & confusion

In the same group
5 members

Literature, links & citation

Citations
  1. 1973Walia, D. S., Chang, L. L. Y. (1973) Investigations in the systems PbS-Sb2S3-As2S3 and PbS-Bi2S3-As2S3. The Canadian Mineralogist, 12 (2) 113-119
  2. 1985Moëlo, Yves, Oudin, Elisabeth, Makovicky, Emil, Karup-Møller, Sven, Pillard, François, Bornuat, Michel, Evanghelou, Evangheli (1985) La kirkiite, Pb10Bi3As3S19, une nouvelle espèce minérale homologue de la jordanite. Bulletin de Minéralogie, 108 (5) 667-677 doi:10.3406/bulmi.1985.7883 DOI: 10.3406/bulmi.1985.7883
  3. 1986Hawthorne, Frank C., Fleischer, Michael, Grew, Edward S., Grice, Joel D., Jambor, John L., Puziewicz, J., Roberts, Andrew C., Vanko, D. A., Zilczer, J. A. (1986) New mineral names. American Mineralogist, 71. 1277-1282
  4. 1990Anthony, Bideaux, Bladh & Nichols (1990), Handbook of Mineralogy, Vol. I.
  5. 1998Borodaev, Yuri S., Garavelli, Anna, Kuzmina, Olga V., Mozgova, Nadezhda N., Organova, Natalia I., Trubkin, Nikolay V., Vurro, Filippo (1998) Rare sulfosalts from Vulcano, Aeolian Islands, Italy. I. Se-bearing kirkiite, Pb10(Bi,As)6(S,Se)19. The Canadian Mineralogist, 36 (4) 1105-1114
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kirkiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kirkiite-2216},
  note      = {Accessed 2026-05-11}
}