Gratonite

Pb9As4S15
IMA status
  • Approved
  • Grandfathered
IMA symbol
Gtn
Discovered
1939
Also known as
  • Gratoniet

Where it forms, where it's found

Geological setting

Hydrothermal copper deposits

Type locality
Excelsior Mine
  1. Cerro de Pasco
  2. Pasco province
  3. Pasco
  4. Peru
33recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Dark lead-gray
Streak
Black
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven · Conchoidal
Density
6.22 g/cm³

Optical

Pleochroism
Weak
Optical colour
White - slightly yellow as compared to galena
Anisotropism
Weak
Tropism
Anisotropic
Reflectance R%
(38.7,39.8) 400, (38.0,39.3) 420, (37.6,38.4) 440, (37.1,37.6) 460, (36.5,36.9) 480, (36.1,36.4) 500, (36.0,36.2) 520, (36.1,36.2) 540, (36.3,36.4) 560, (36.6,36.6) 580, (36.7,36.7) 600, (36.3,36.4) 620, (35.7,35.8) 640, (34.8,35.0) 660, (33.8,34.1) 680, (33.0,33.3) 700
Reflected-light panel
36.2 %anisotropic · dual curve
Specimen sRGB 215, 150, 84
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Weak
Reflected colour
White - slightly yellow as compared to galena

Crystallography

Crystal system
Trigonal
Space group
#86
Cell parameters
a = 17.758(14) Å · c = 7.807(6) Å
Z
3
Morphology

Prismatic crystals, massive. Type material: A hexagonal prism {11.0} and a trigonal pyramid {02.1} are the primary forms, with some crystals showing narrow and always brilliant truncation of the edges of the principal trigonal pyramid {10.1} and minute brilliant facets of a steeper pyramid {40.1}. One crystal showed a flat trigonal pyramid {01.2} at the termination, another showed a steep ditrigonal pyramid {24.1}(?) between the prism and main pyramid. A few other rare forms are are listed.

Type-locality form

Slender needles 0.1 mm in diameter and 0.5 mm in length to stout prisms 1 cm across and 1.5 cm in length. Generally in radiating groups.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead9207.2001864.800
70.49%
16SSulfurSulfur1532.060480.900
18.18%
33AsArsenicArsenic474.922299.688
11.33%
Total2645.388100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Sb

Synonyms

  • Gratoniet

In other languages

German
Gratonit
Spanish
gratonita
Italian
Gratonite
Chinese
细硫砷铅矿
Simplified Chinese
细硫砷铅矿
Traditional Chinese
細硫砷鉛礦

Classification

Strunz
10th ed.

2.JB.55

  • 2Sulfides and SulfosaltsClass
  • 2.JSulfosalts of PbS archetypeDivision
  • 2.JBGalena derivatives, with PbGroup
  • 2.JB.55GratoniteSpecies
Dana
8th ed.

03.03.02.01

  • 03SulfosaltsClass
  • 03.033 <ø < 4Type
  • 03.03.02— unnamed intermediate level —Group
  • 03.03.02.01GratoniteSpecies
CIM

5.6.5

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.6Sulpharsenites etc. of Pb aloneGroup
  • 5.6.5GratoniteSpecies

Group, growth & confusion

In the same group
5 members
Often grow together
6 minerals

Literature, links & citation

Citations
  1. 1939Palache, Charles; Fisher, D. Jerome (1939) Gratonite - preliminary description of a new mineral from Cerro de Pasco, Peru. American Mineralogist, 24 (2). 136
  2. 1940Palache, Charles; Fisher, D. Jerome (1940) Gratonite - a new mineral from Cerro de Pasco, Peru. American Mineralogist, 25 (4). 255-265
  3. 1940Rust, George W. (1940) Geologic occurrence of gratonite at Cerro de Pasco, Peru. American Mineralogist, 25 (4) 266-270
  4. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  5. 1963Rösch, H. (1963) Zur Kristallstruktur des Gratonits - 9PbS2As2S3. Doctoral dissertation, Verlag nicht ermittelbar.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Gratonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/gratonite-1741},
  note      = {Accessed 2026-05-11}
}