Kröhnkite

Na2Cu(SO4)2 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Khk
Also known as
  • Kroehnkite
  • Kröhnkiet
  • Krömkite
  • +2 more

Where it forms, where it's found

Type locality
Chuquicamata Mine
  1. Chuquicamata District
  2. Calama
  3. El Loa Province
  4. Antofagasta
  5. Chile

-22.2894°, -68.9011°

34recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Blue · greenish-blue · light blue to colourless in transmitted light
Streak
White
Cleavage
Perfect

On (010) perfect; on {1¯01} very imperfect.

Fracture
Conchoidal
Density
2.90 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 78° · 2V calc = 76°
Refractive index
1.544 – 1.601
Surface relief
Moderate
Principal indices
nα 1.544 · nβ 1.578 · nγ 1.601
Dispersion
weak
Michel-Lévy diagramhighlighted lineδ = 0.0570
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]570 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation570 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 5.807(1) Å · b = 12.656(2) Å · c = 5.517(1) Å
Cell angles
β = 108.32(1) °
Ratio a:b:c
1 : 2.179 : 0.950
Morphology

Crystals short prismatic [001]; also octahedral with large (110) and (011) and rather elongated [100]. Prismatic or fibrous aggregates and crusts; massive, granular.

Twinning

On (101), common; twins heart-shaped at times.

Comment

Cell data from Hawthorne and Ferguson (1975).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
47.38%
16SSulfurSulfur232.06064.120
18.99%
29CuCopperCopper163.54663.546
18.82%
11NaSodiumSodium222.99045.980
13.62%
1HHydrogenHydrogen41.0084.032
1.19%
Total337.668100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Kroehnkite
  • Kröhnkiet
  • Krömkite
  • Krönnkite
  • Salvadorite (of Herz)

In other languages

French
Kröhnkite
German
Kröhnkit
Spanish
Kröhnkita
Italian
Kroehnkite · Kröhnkite

Classification

Strunz
10th ed.

7.CC.30

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CCWith medium-sized and large cationsGroup
  • 7.CC.30KröhnkiteSpecies
Dana
8th ed.

29.03.02.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.03A2B(XO4)2·xH2OType
  • 29.03.02— unnamed intermediate level —Group
  • 29.03.02.01KröhnkiteSpecies
CIM

25.2.11

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.11KröhnkiteSpecies

Group, growth & confusion

In the same group
6 members

Literature, links & citation

Citations
  1. 1860Domeyko, Ignacio (1860) Elementos de Mineralojia [Elements of Mineralogy] (2nd ed.) Ferrocarril, Santiago.
  2. 1879Domeyko, I. (1879) Elementos de Mineralogia, 3rd. edition: 250 (as Krönnkite).
  3. 1889Darapsky (1889) Neues Jahrbuch für Mineralogie, Geologie und Paleontologie, Heidelberg, Stuttgart: I: 192.
  4. 1896Herz (1896) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 26: 16 (as Salvadorite).
  5. 1908Palache, C., Warren, C.H. (1908) Kröhnkite, natrochalcite (a new mineral), and other sulphates from Chile. American Journal Of Science, S. 4 Vol. 26. 342-348
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Kröhnkite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/krohnkite-2277},
  note      = {Accessed 2026-05-11}
}