Rruffite

Ca2Cu(AsO4)2 · 2H2O
IMA status
  • Approved
IMA symbol
Ruf
IMA approved
2010
Also known as
  • IMA2009-077
  • Rruffiet

Where it forms, where it's found

Geological setting

The oxydation zone of a Cu-As orebody.

Type locality
Maria Catalina mine
  1. Pampa Larga mining district
  2. Tierra Amarilla
  3. Copiapó Province
  4. Atacama
  5. Chile

-27.6042°, -70.1669°

4recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Pale blue · light blue
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (010).

Density
3.79 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 80° · 2V calc = 78°
Refractive index
1.725 – 1.74
Surface relief
High
Principal indices
nα 1.725 · nβ 1.734 · nγ 1.740
Dispersion
Weak, r < v
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 5.8618(2) Å · b = 12.7854(5) Å · c = 5.7025(2) Å
Cell angles
β = 109.425(2) °
Ratio a:b:c
1 : 2.181 : 0.973
Morphology

In granular or blocky aggregates and druses.

Twinning

Common on (100)

Type-locality form

Secondary mineral.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
34.96%
33AsArsenicArsenic274.922149.844
32.75%
20CaCalciumCalcium240.07880.156
17.52%
29CuCopperCopper163.54663.546
13.89%
1HHydrogenHydrogen41.0084.032
0.88%
Total457.568100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2009-077
  • Rruffiet

In other languages

German
IMA 2009-077 · Rruffit
Italian
rruffite

Classification

Strunz
10th ed.

8.CG.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CGWith large and medium-sized cations, RO4:H2O = 1:1Group
  • 8.CG.10RruffiteSpecies
Dana
8th ed.

40.02.04.05

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.02AB2(XO4)2·xH2OType
  • 40.02.04— unnamed intermediate level —Group
  • 40.02.04.05RruffiteSpecies

Group, growth & confusion

In the same group
6 members

Literature, links & citation

Citations
  1. 2011Yang, H., Jenkins, R. A., Downs, R. T., Evans, S. H., Tait, K. T. (2011) Rruffite, Ca2Cu(AsO4)2·2H2O,a new member of the roselite group, from Tierra Amarilla, Chile. The Canadian Mineralogist, 49 (3) 877-884 doi:10.3749/canmin.49.3.877 DOI: 10.3749/canmin.49.3.877
  2. 2022(2022) Rruffite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2024Biagioni, C., Mugnaioli, E., Lorenzon, S., Mauro, D., Musetti, S., Sejkora, J., Belmonte, D., Demitri, N., Dolníček, Z. (2024) Nannoniite, IMA 2024-010, in IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 80. European Journal of Mineralogy, 36 (4). 599-604 doi:10.5194/ejm-36-599-2024DOI: 10.5194/ejm-36-599-2024
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Rruffite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/rruffite-39845},
  note      = {Accessed 2026-05-11}
}