Liottite

Na16Ca8Si18Al18O72(SO4)5Cl4
IMA status
  • Approved
IMA symbol
Lio
Discovered
1975
IMA approved
1975
Also known as
  • IMA1975-036
  • Liottiet

Where it forms, where it's found

Geological setting

In cavities of ejected blocks in a pumice deposit.

Type locality
Case Collina
  1. Pitigliano
  2. Grosseto Province
  3. Tuscany
  4. Italy

42.6425°, 11.7303°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Colourless
Streak
White
Density
2.56 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.528 – 1.53
Surface relief
Moderate
Principal indices
nω 1.53 · nε 1.528
Michel-Lévy diagramhighlighted lineδ = 0.0020
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]20 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation20 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#100
Cell parameters
a = 12.870(1) Å · c = 16.096(2) Å
Morphology

(001), (100), (110), (101), (102), (103), (104), (203), (111), and minor forms (120), (121), (112), (113).

Type-locality form

Flattened hexagonal prisms up to 1 cm in diameter.

Comment

Cell parameters from Ballirano et al. (1996).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen9215.9991471.908
42.62%
14SiSiliconSilicon1828.085505.530
14.64%
13AlAluminiumAluminium1826.982485.676
14.06%
11NaSodiumSodium1622.990367.840
10.65%
20CaCalciumCalcium840.078320.624
9.28%
16SSulfurSulfur532.060160.300
4.64%
17ClChlorineChlorine435.450141.800
4.11%
Total3453.678100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe

Synonyms

  • IMA1975-036
  • Liottiet

In other languages

German
IMA 1975-036 · Liottit
Italian
Liottite

Classification

Strunz
10th ed.

9.FB.05

  • 9SilicatesClass
  • 9.FTektosilicates without zeolitic H2ODivision
  • 9.FBTektosilicates with additional anionsGroup
  • 9.FB.05LiottiteSpecies
Dana
8th ed.

76.02.05.09

  • 76Tectosilicates Al-si FrameworkClass
  • 76.02Al-Si Framework Feldspathoids and related speciesType
  • 76.02.05Cancrinite groupGroup
  • 76.02.05.09LiottiteSpecies
CIM

17.10.5

  • 17Silicates Containing other AnionsClass
  • 17.10Silicates with sulphate, molybdate or tungstateGroup
  • 17.10.5LiottiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1977Merlino, Stefano, Orlandi, Paolo (1977) Liottite, a new mineral in the cancrinite-davyne group. American Mineralogist, 62 (3-4) 321-326
  2. 1979Leoni, L., Mellini, M., Merlino, S., Orlandi, P. (1979) Cancrinite-like minerals: new data and crystal chemical considerations. Rendiconti della Società Italiana di Mineralogia e Petrologia: 35: 713-719.
  3. 1979Rinaldi, R., Wenk, H. R. (1979) Stacking variations in cancrinite minerals. Acta Crystallographica Section A: Crystal Physics, Diffraction, Theoretical and General Crystallography, 35 (5). 825-828 doi:10.1107/s0567739479001868DOI: 10.1107/s0567739479001868
  4. 1984Hassan, I., Grundy, H. D. (1984) The crystal structures of sodalite-group minerals. Acta Crystallographica Section B Structural Science, 40 (1) 6-13 doi:10.1107/s0108768184001683DOI: 10.1107/s0108768184001683
  5. 1996Ballirano, P., Merlino, S., Bonaccorsi, E., Maras, A. (1996) The crystal structure of liottite, a six-layer member of the cancrinite group. The Canadian Mineralogist, 34 (5) 1021-1030
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Liottite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/liottite-2411},
  note      = {Accessed 2026-05-11}
}