Litidionite

KNaCuSi4O10
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ltd
Discovered
1880
Also known as
  • Lithidionit
  • Lithidionita
  • Lithidionite
  • +5 more

Where it forms, where it's found

Geological setting

In lapilli modified by fumarolic activity.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Density
2.75 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 56°
Refractive index
1.548 – 1.574
Surface relief
Moderate
Principal indices
nα 1.548 · nβ 1.574
Dispersion
none

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 9.80(1) Å · b = 8.01(1) Å · c = 6.97(1) Å
Cell angles
α = 114.12(8) ° · β = 99.52(6) ° · γ = 105.59(8) °
Ratio a:b:c
1 : 0.817 : 0.711
Z
2
Type-locality form

Very tiny blue plates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
40.20%
14SiSiliconSilicon428.085112.340
28.23%
29CuCopperCopper163.54663.546
15.97%
19KPotassiumPotassium139.09839.098
9.82%
11NaSodiumSodium122.99022.990
5.78%
Total397.964100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Pb
  • Ca

Synonyms

  • Lithidionit
  • Lithidionita
  • Lithidionite
  • Litidioniet
  • Neociano
  • Neocyanit
  • Neocyanita
  • Neocyanite

In other languages

German
Lithidionit · Litidionit · Neocyanit
Spanish
Litidionita
Italian
lithidionite · litidionite

Classification

Strunz
10th ed.

9.DG.70

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DGInosilicates with 3-periodic single and multiple chainsGroup
  • 9.DG.70LitidioniteSpecies
Dana
8th ed.

70.01.01.01

  • 70Inosilicates Column or Tube StructuresClass
  • 70.01Column or Tube Structures with columnar silicate unitsType
  • 70.01.01Litidionite groupGroup
  • 70.01.01.01LitidioniteSpecies
CIM

14.2.6

  • 14Silicates not Containing AluminumClass
  • 14.2Silicates of CuGroup
  • 14.2.6LitidioniteSpecies

Group, growth & confusion

In the same group
4 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1880Scacchi, E. (1880) Lapilli azzurri del Vesuvio. Atti della Regia Accademia delle Scienze Fisiche e Matematiche di Napoli: 19: 175-179.
  2. 1882Scacchi, A. (1882) Nuovi sublimati del cratere vesuviano trovati nel mese di ottobre del 1880 (Memoria 1880). Atti della Reale Accademia delle Scienze Fisiche e Matematiche di Napoli, Serie 1: 9: 1-10.
  3. 1935Zambonini, F. (1935) Mineralogia Vesuviana, S.I.E.M. Naples: 435-439.
  4. 1975Pozas, Jose M. Martin, Rossi, Giuseppe, Tazzoli, Vittorio (1975) Re-examination and crystal structure analysis of litidionite. American Mineralogist, 60 (5-6) 471-474
  5. 1977Kawamura, K., Kawahara, A. (1977) The crystal structure of synthetic copper sodium silicate: CuNa2Si4O10. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 33 (4) 1071-1075 doi:10.1107/s0567740877005391DOI: 10.1107/s0567740877005391
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Litidionite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/litidionite-2422},
  note      = {Accessed 2026-05-11}
}