Ludjibaite

Cu5(PO4)2(OH)4
IMA status
  • Approved
IMA symbol
Ldj
Discovered
1987
IMA approved
1987
Also known as
  • IMA1987-009
  • Ludjibaiet

Where it forms, where it's found

Type locality
Ludjiba prospect
  1. Shinkolobwe
  2. Kambove Territory
  3. Haut-Katanga
  4. DR Congo

-10.9702°, 26.5572°

20recorded occurrences
Source · OpenStreetMap

Physical

Lustre
Vitreous
Transparency
Translucent · Opaque
Colour
Blue-green
Streak
Pale blue to white
Fracture
Irregular/Uneven
Density
4.36 g/cm³

Optical

Optical type
Biaxial (+/-)
Refractive index
1.786 – 1.84
Surface relief
Very high
Principal indices
nα 1.786 · nγ 1.84
Dispersion
extreme
Michel-Lévy diagramhighlighted lineδ = 0.0540
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]540 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation540 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 4.44 Å · b = 5.87 Å · c = 8.68 Å
Cell angles
α = 103.9 ° · β = 90.3 ° · γ = 93.2 °
Ratio a:b:c
1 : 1.322 : 1.955
Morphology

As bladed crystals, flattened on (011).

Twinning

On (011).

Type-locality form

Aggregates of blades

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper563.546317.730
55.19%
8OOxygenOxygen1215.999191.988
33.35%
15PPhosphorusPhosphorus230.97461.948
10.76%
1HHydrogenHydrogen41.0084.032
0.70%
Total575.698100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1987-009
  • Ludjibaiet

In other languages

German
IMA 1987-009 · Ludjibait
Italian
Ludjibaite
Portuguese
IMA1987-009 · Ludjibaíta

Classification

Strunz
10th ed.

8.BD.25

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BDWith only medium-sized cations, (OH, etc.):RO4= 2:1Group
  • 8.BD.25LudjibaiteSpecies
Dana
8th ed.

41.04.03.03

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.04(AB)5(XO4)2ZqType
  • 41.04.03— unnamed intermediate level —Group
  • 41.04.03.03LudjibaiteSpecies
CIM

19.2.4

  • 19PhosphatesClass
  • 19.2Phosphates of CuGroup
  • 19.2.4LudjibaiteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1981Shoemaker, Gerald L., Anderson, James B., Kostiner, Edward (1981) The crystal structure of a third polymorph of Cu5(PO4)2(OH)4. American Mineralogist, 66 (1-2) 169-175
  2. 1988Piret, Paul, Deliens, Michel (1988) Description de la ludjibaïte, un polymorphe de la pseudomalachite, Cu5(PO4)2(OH)4. Bulletin de Minéralogie, 111 (2) 167-171 doi:10.3406/bulmi.1988.8081DOI: 10.3406/bulmi.1988.8081
  3. 1988Jambor, John L., Ercit, Ernst A. J. Burke T. Scott, Grice, Joel D. (1988) New Mineral Names. American Mineralogist, 73 (11-12) 1492-1499
  4. 1991Hyršl, J. (1991) Three polymorphs of Cu5(PO4)2(OH)4 from Ľubietová, Czechoslovakia. Neues Jahrbuch für Mineralogie - Monatshefte, 1991 (6) 281-287
  5. 2002Frost, Ray L., Williams, Peter A., Martens, Wayde, Kloprogge, J. Theo, Leverett, Peter (2002) Raman spectroscopy of the basic copper phosphate minerals cornetite, libethenite, pseudomalachite, reichenbachite and ludjibaite. Journal of Raman Spectroscopy, 33 (4). 260-263 doi:10.1002/jrs.850DOI: 10.1002/jrs.850
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ludjibaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ludjibaite-2451},
  note      = {Accessed 2026-05-11}
}