Pseudomalachite

Cu5(PO4)2(OH)4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pmlc
Discovered
1813
Also known as
  • Cuivre Phosphaté
  • Dihydrite
  • Ehlit
  • +24 more

History

The name is a confession of mistaken identity. Pseudomalachite joins the Greek pseudes — false — to the name of malachite, the deep-green copper mineral it so closely resembles. The two look almost alike: both are green crusts that form where copper ore meets air and water. But malachite is a carbonate, a copper mineral built around carbon and oxygen, while pseudomalachite is a phosphate, built around phosphorus instead. Drop a little acid on malachite and it fizzes; pseudomalachite stays quiet. The name records the resemblance and the warning in one word.

The mineral was first recognised in 1813. Its defining specimens came from the Virneberg Mine at Rheinbreitbach, in the Westerwald hills of western Germany. That original material is still kept at the Mining Academy in Freiberg.

For more than a century afterward, the same green phosphate kept being described under different names. Specimens were catalogued as dihydrite, lunnite, ehlite, tagilite, and prasin, each treated as a separate species. In 1950 the mineralogist L. G. Berry examined samples bearing all these labels, drawn from several museum collections, and showed that every one of them was simply pseudomalachite. Five names collapsed into one.

Industrial & practical applications

Pseudomalachite has no industrial use of its own. It forms only as a secondary mineral in the oxidised zones of copper ore deposits — the weathered upper layers where copper has reacted with air and water. Where it occurs, it is a copper-bearing mineral, so it adds in a small way to the copper an ore yields. But it never gathers in the quantities a mine would target, and nothing is extracted for it specifically. Its main draw is for collectors, who prize its deep green crusts.

Where it forms, where it's found

Geological setting

Oxidized zones of copper deposits.

Type locality
Virneberg Mine
  1. Rheinbreitbach
  2. Unkel
  3. Neuwied
  4. Rhineland-Palatinate
  5. Germany

50.6178°, 7.2494°

399recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Blue-green · green · dark green · green-black · green to bluish green in transmitted light.
Streak
Blue-green
Cleavage
Imperfect/Fair

Imperfect on the (010).

Fracture
Splintery · Conchoidal
Density
3.6 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 48° · 2V calc = 42°
Refractive index
1.791 – 1.867
Surface relief
Very high
Principal indices
nα 1.791 · nβ 1.856 · nγ 1.867
Dispersion
r > v perceptible
Extinction
Z = b; X ∧ c = 21°–23°.
UV response
None.
Michel-Lévy diagramhighlighted lineδ = 0.0760
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]760 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation760 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 4.47 Å · b = 5.75 Å · c = 17.05 Å
Cell angles
β = 91.06 °
Ratio a:b:c
1 : 1.286 : 3.814
Unit cell volume
441.14 ų
Z
2
Morphology

Usually occurs as botryoidal crusts; hemispherical aggregates of microscopic crystals; sub-parallel aggregates with a drusy surface. Individual crystals are rare, prismatic [001], usually with uneven faces; small, tabular crystals (Manto Cuba Mine, Chile). Also occurs as reniform, botryoidal or massive with a radial-fibrous structure and concentric banding, the fibers elongated [010]; foliated; microcrystalline or dense; colloform.

Twinning

On (100).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper563.546317.730
55.19%
8OOxygenOxygen1215.999191.988
33.35%
15PPhosphorusPhosphorus230.97461.948
10.76%
1HHydrogenHydrogen41.0084.032
0.70%
Total575.698100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Cuivre Phosphaté
  • Dihydrite
  • Ehlit
  • Ehlite
  • Hypoleimme
  • Kupfer-Diaspor
  • Kupfer-diaspore
  • Lunnit
  • Phosphate of Copper
  • phosphochalcite
  • Phosphor-kupfererz
  • Phosphorchalcit
  • Phosphorchalcite
  • Phosphorkupfer
  • Phosphorocalcit
  • Phosphorochalcit
  • Phosphorokalzit
  • Phosphorsaures Kupfer
  • Phosphorsaures Kupferoxyd
  • Prasin
  • Prasin-chalzit
  • Pseudomalaquite
  • Rhenit
  • Rhenite
  • Tagilite
  • Tagilith
  • Ypoléime

In other languages

German
Pseudomalachit
Spanish
Pseudomalaquita
Italian
Pseudomalachite
Japanese
シュードマラカイト
Russian
Псевдомалахит

Classification

Strunz
10th ed.

8.BD.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BDWith only medium-sized cations, (OH, etc.):RO4= 2:1Group
  • 8.BD.05PseudomalachiteSpecies
Dana
8th ed.

41.04.03.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.04(AB)5(XO4)2ZqType
  • 41.04.03— unnamed intermediate level —Group
  • 41.04.03.01PseudomalachiteSpecies
CIM

19.2.5

  • 19PhosphatesClass
  • 19.2Phosphates of CuGroup
  • 19.2.5PseudomalachiteSpecies

Group, growth & confusion

Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. Wallerius (as Kupfergrün, in part).
  2. 1801Klaproth (1801) Ges. nat. Freunde Berlin, N. Schr.: 3: 304 (as Phosphorsaures Kupfer).
  3. 1808Karsten, D.L.G. (1808) Mineralogische Tabellen, Berlin. second edition: 64, 97 (as Phosphorkupfer).
  4. 1809Haüy, René Just (1809) Tableau comparatif des résultats de la Cristallographie et de l'analyse Chimique, relativement a la Classification des Minéraux.. Chez Courcier, Paris.
  5. 1813Hausmann, Johann Friedrich Ludwig (1813) Handbuch der Mineralogie (1st ed.). Vandenhoeck und Ruprecht.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pseudomalachite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pseudomalachite-3299},
  note      = {Accessed 2026-05-11}
}