Mackinawite

FeS
IMA status
  • Approved
IMA symbol
Mkw
Discovered
1962
Also known as
  • Kansite (of Meyer et al.)
  • Mackinawiet

Where it forms, where it's found

Geological setting

deeply weathered serpentinite

Widespread in low-temperature aqueous systems. It often occurs as one of the principal constituents of acid volatile sulfides in marine sediments. Rarely in carbonaceous chondrite meteorites.

Type locality
Mackinaw Mine
  1. Monte Cristo Mining District
  2. Snohomish County
  3. Washington
  4. USA

47.9814°, -121.4419°

476recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Bronzy
Streak
Black
Cleavage
Perfect

Perfect on (001).

Density
4.17 g/cm³

Optical

Pleochroism
Strong
Anisotropism
extreme
Tropism
Anisotropic
Reflectance R%
(17.7,25.7) 400, (17.0,28.0) 420, (16.4,30.2) 440, (16.2,32.2) 460, (16.1,34.4) 480, (16.0,36.5) 500, (16.1,38.4) 520, (16.1,40.0) 540, (16.3,41.4) 560, (16.5,42.5) 580, (16.7,43.3) 600, (17.0,43.9) 620, (17.2,44.3) 640, (17.4,44.5) 660, (17.5,44.6) 680, (17.7,44.6) 700
Reflected-light panel
16.7 %anisotropic · dual curve
Specimen sRGB 153, 103, 55
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
extreme

Crystallography

Crystal system
Tetragonal
Space group
#185
Cell parameters
a = 3.67 Å · c = 5.03 Å
Unit cell volume
68 ų
Z
2
Morphology

As well-formed thin tabular crystals, to 1 mm; massive, fine-feathery.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron155.84555.845
63.53%
16SSulfurSulfur132.06032.060
36.47%
Total87.905100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Co
  • Cu
  • Ni

Synonyms

  • Kansite (of Meyer et al.)
  • Mackinawiet

In other languages

French
Mackinawite
German
Mackinawit
Spanish
Mackinawita
Italian
Mackinawite
Russian
макинавит

Classification

Strunz
10th ed.

2.CC.25

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CCWith Ni, Fe, Co, PGE, etc.Group
  • 2.CC.25MackinawiteSpecies
Dana
8th ed.

02.07.02.01

  • 02SulfidesClass
  • 02.07AmBnXp, with (m+n):p = 9:8Type
  • 02.07.02— unnamed intermediate level —Group
  • 02.07.02.01MackinawiteSpecies
CIM

3.9.6

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.9Sulphides etc. of FeGroup
  • 3.9.6MackinawiteSpecies

Group, growth & confusion

Often grow together
4 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1962Evans, H.T., Jr., Berner, R.A., Milton, Charles (1962) Valleriite and mackinawite(abs.). Geological Society of America, Program 1962 Meeting, p.47A.
  2. 1963Fleischer, Michael (1963) New Mineral Names. American Mineralogist, 48 (1-2) 209-217
  3. 1963Kouvo, Olavi, Vuorelainen, Yrjo, Long, J. V. P. (1963) A tetragonal iron sulfide. American Mineralogist, 48 (5-6) 511-524
  4. 1964Fleischer, M. (1964) New Mineral Names. American Mineralogist, 49 (9-10) 1497-1502
  5. 1964Evans, H.T., Milton, C., Chao, E.C.T., Adler, I., Mead, C., Ingram, B., Berner, R.A. (1964) Valleriite and the new iron sulfide, mackinawite. U.S. Geological Survey Professional Paper, 475-D: 64-69.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mackinawite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mackinawite-2512},
  note      = {Accessed 2026-05-11}
}