Makarochkinite

Ca4[Fe2+8Fe3+2Ti2]O4[Si8Be2Al2O36]
IMA status
  • Approved
IMA symbol
Mkr
IMA approved
2003
Also known as
  • IMA2002-009a
  • Makarochkiniet

Where it forms, where it's found

Geological setting

granitic pegmatite

Type locality
Pit No. 400
  1. Argayashsky District
  2. Chelyabinsk Oblast
  3. Russia

55.2997°, 60.2489°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789105.5 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
black
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.93 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.821 – 1.88
Surface relief
Very high
Principal indices
nα 1.821 – 1.849 · nγ 1.85 – 1.88
Pleochroism
Visible

X = greenish brown, Y = yellowish brown, Z = reddish brown; Y ≤ X < Z

Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#1
Cell parameters
a = 10.355 Å · b = 10.751 Å · c = 8.873 Å
Cell angles
α = 105.707 ° · β = 96.227 ° · γ = 124.861 °
Ratio a:b:c
1 : 1.038 : 0.857
Unit cell volume
735.7 ų
Z
2
Twinning

absent

Type-locality form

equant masses, 5-50 mm across

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4015.999639.960
36.55%
26FeIronIron1055.845558.450
31.89%
14SiSiliconSilicon828.085224.680
12.83%
20CaCalciumCalcium440.078160.312
9.15%
22TiTitaniumTitanium247.86795.734
5.47%
13AlAluminiumAluminium226.98253.964
3.08%
4BeBerylliumBeryllium29.01218.024
1.03%
Total1751.124100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Na
  • Mn
  • Mg

Synonyms

  • IMA2002-009a
  • Makarochkiniet

In other languages

German
IMA 2002-009a · Makarochkinit
Italian
makarochkinite

Classification

Strunz
10th ed.

9.DH.40

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DHInosilicates with 4-periodic single chains, Si4O12Group
  • 9.DH.40MakarochkiniteSpecies

Group, growth & confusion

In the same group
5 members

Literature, links & citation

Citations
  1. 1986Polyakov, V.O., Cherepivskaya, G.Ye. & Shcherbakova, Ye.P., (1986): Makarochkinite – a new beryllosilicate. In New and little-studied minerals and mineral associations of the Urals. Akad Nauk SSSR Ural’skiy Nauchnyy Tsentr. Sverdlovsk: 108–110. (in Russian)
  2. 2004Friis, Henrik, Balzic-Zunich, T., Finch, A. (2004) A structural and luminescence study of leucophanite, NaCaBeSi2O6F. GFF, 126 (1) 67-68 doi:10.1080/11035890401261sn8DOI: 10.1080/11035890401261sn8
  3. 2005Grew, E. S. (2005) Makarochkinite, Ca2Fe42+Fe3+TiSi4BeAlO20, a new beryllosilicate member of the aenigmatite-sapphirine-surinamite group from the Il'men Mountains (southern Urals), Russia. American Mineralogist, 90 (8) 1402-1412 doi:10.2138/am.2005.1759 DOI: 10.2138/am.2005.1759
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Makarochkinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/makarochkinite-2547},
  note      = {Accessed 2026-05-11}
}