Mangano-ferri-eckermannite

NaNa2(Mn2+4Fe3+)Si8O22(OH)2
IMA status
  • Approved
IMA symbol
Mfeck
Discovered
1969
IMA approved
1969
Also known as
  • Kozulit
  • Kozulita
  • Kôzulite
  • +1 more

Where it forms, where it's found

Geological setting

Metasedimentary manganese ore.

Type locality
Tanohata mine
  1. Tanohata
  2. Shimohei District
  3. Iwate Prefecture
  4. Japan

39.9167°, 141.9000°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Colour
Reddish-black to black.
Streak
Light purplish-brown.
Cleavage
Perfect

on (110)

Density
3.30 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 34 – 36° · 2V calc = 32°
Refractive index
1.685 – 1.72
Surface relief
High
Principal indices
nα 1.685 · nβ 1.717 · nγ 1.72
Pleochroism
Strong

X yellow-brown, Y reddish brown, Z dark brown,

Dispersion
r > v
Luminescence
Nonfluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0350
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]350 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation350 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 9.99 Å · b = 18.11 Å · c = 5.3 Å
Cell angles
β = 104.6 °
Ratio a:b:c
1 : 1.813 : 0.531
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
40.20%
14SiSiliconSilicon828.085224.680
23.52%
25MnManganeseManganese454.938219.752
23.00%
11NaSodiumSodium322.99068.970
7.22%
26FeIronIron155.84555.845
5.85%
1HHydrogenHydrogen21.0082.016
0.21%
Total955.239100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cr
  • Zn
  • Mg
  • Ca
  • K
  • H2O

Synonyms

  • Kozulit
  • Kozulita
  • Kôzulite
  • Mangano-ferri-eckermanniet

In other languages

German
Mangano-Ferri-Eckermannit
Italian
kozulite · mangano-ferri-eckermannite
Japanese
マンガノ第二鉄エカーマン閃石 · 神津閃石

Classification

Strunz
10th ed.

9.DE.25

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DEInosilicates with 2-periodic double chains, Si4O11; ClinoamphibolesGroup
  • 9.DE.25Mangano-ferri-eckermanniteSpecies
Dana
8th ed.

66.01.3c.10

  • 66Inosilicates Double-width, Unbranched Chains, (w=2)Class
  • 66.01Amphiboles - Mg-Fe-Mn-Li subgroupType
  • 66.01.3c— unnamed intermediate level —Group
  • 66.01.3c.10Mangano-ferri-eckermanniteSpecies
CIM

16.16.10

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.16Aluminosilicates of MnGroup
  • 16.16.10Mangano-ferri-eckermanniteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. Acta Crystallographica: A28: 71.
  2. 1968Nambu, M. et al (1968) Manganese alkaliamphibole from Tanohata mine, Iwate prefecture, Japan. Journal of the Mineralogical Society of Japan: 9: 18.
  3. 1969Nambu, Matsuo, Tanida, Katsutoshi, Kitamura, Tsuyoshi (1969) Kôzulite, a new alkali amphibole, from Tanohata Mine, Iwate Prefecture, Japan. The Journal of the Japanese Association of Mineralogists, Petrologists and Economic Geologists, 62 (6) 311-328 doi:10.2465/ganko1941.62.311 DOI: 10.2465/ganko1941.62.311
  4. 1969Nambu, M. et al (1969) Some Mn-bearing amphiboles from Kitakami massif, Japan. Journal of the Japanese Association of Mineralogists, Petrologists and Economic Geologists: 61: 169.
  5. 1970Fleischer, M., Nickel, E.H. (1970) New mineral names. American Mineralogist: 55: 1810-1818.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mangano-ferri-eckermannite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mangano-ferri-eckermannite-2267},
  note      = {Accessed 2026-05-11}
}