Mariakrite

[Ca4Al2(OH)12(H2O)4][Fe2S4]
IMA status
  • Approved
IMA symbol
Mari
Also known as
  • IMA2021-097
  • Mariakriet

Where it forms, where it's found

Geological setting

late hydrothermal assemblages confined to pyrometamorphic lithologies of the Hatrurim Formation

Type locality
Hatrurim Junction (road no. 31)
  1. Hatrurim Basin
  2. Tamar Regional Council
  3. Beersheba Subdistrict
  4. Southern District
  5. Israel

31.2019°, 35.2615°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
purple-brown

in transmitted light, it is transparent green-grey

Tenacity
flexible
Cleavage

flexible, elastic

Density
2.005 g/cm³

Optical

Pleochroism
Strong

extreme gray to red-purple

Anisotropism
very strong
Tropism
Anisotropic
Reflectance R%
(5.0,5.2) 470, (6.3,2.3) 546, (6.7,1.8) 589, (6.6,17.6) 659
Reflected-light panel
6.2 %anisotropic · dual curve
Specimen sRGB 100, 65, 26
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
very strong

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.7107(2) Å · b = 9.9952(4) Å · c = 10.9095(4) Å
Cell angles
α = 98.678(3) ° · β = 90.100(3) ° · γ = 90.019(3) °
Ratio a:b:c
1 : 1.750 : 1.910
Z
1
Type-locality form

saber-like crystals up to 2 mm long, 0.1 mm wide and 0.5 to 2 μm thick, residing in millimeter-sized cavities

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
35.05%
20CaCalciumCalcium440.078160.312
21.95%
16SSulfurSulfur432.060128.240
17.56%
26FeIronIron255.845111.690
15.29%
13AlAluminiumAluminium226.98253.964
7.39%
1HHydrogenHydrogen201.00820.160
2.76%
Total730.350100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2021-097
  • Mariakriet

In other languages

German
IMA 2021-097 · Mariakrit
Italian
Mariakrite
Japanese
マリアクリテ

Classification

Strunz
10th ed.

4.FL

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FLHydroxides with H2O +- (OH); sheets of edge-sharing octahedraGroup
  • 4.FLMariakriteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 2022(2022) Mariakrite. Handbook of Mineralogy. Mineralogical Society of America
  2. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 65. European Journal of Mineralogy, 34 (1) 143-148 doi:10.5194/ejm-34-143-2022 DOI: 10.5194/ejm-34-143-2022
  3. 2025Murashko, Mikhail N.; Vapnik, Yevgeny; Vlasenko, Natalia S.; Vereshchagin, Oleg S.; Shelukhina, Yulia S.; Pekov, Igor V.; Britvin, Sergey N. (2025) Mariakrite, [Ca4Al2(OH)12(H2O)4][Fe2S4], a new mineral, the first layered double hydroxide intercalated with dithioferrate (iron disulfide) chains. American Mineralogist, 110 (9). 1488-1497 doi:10.2138/am-2024-9624DOI: 10.2138/am-2024-9624
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mariakrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mariakrite-55766},
  note      = {Accessed 2026-05-11}
}