Marioantofilliite

[Cu4Al2(OH)12](CO3)·3H2O
IMA status
  • Approved
IMA symbol
Maf
Also known as
  • IMA2025-012
  • Marioantofilliiet

Where it forms, where it's found

Geological setting

The Monte Copello prospect exploited a sulfide ore body, mainly represented by pyrite and chalcopyrite within a gangue of calcite, quartz, and clay minerals, at the tectonized contact between basalts and Calpionella limestone. The ore body is deeply weathered, and it is represented by gossan.

Type locality
Monte Copello-Reppia mine
  1. Reppia
  2. Ne
  3. Genoa
  4. Liguria
  5. Italy

44.3864°, 9.4569°

2recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Blue · green

Green in case of elevated Fe contents (https://lavrion.gr/Minerals/M/Marioantofilliite.html).

Streak
light blue
Tenacity
brittle
Cleavage
None Observed
Fracture
None observed
Density
2.825 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 69 – 72°
Refractive index
1.613 – 1.633
Surface relief
Moderate
Principal indices
nα 1.613 · nβ 1.626 · nγ 1.633
Pleochroism
Visible

X = colourless and Z = pale blue

Dispersion
strong, with r>v
UV response
does not fluoresce under short- and long-wavelength UV radiation.
Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 5.590(3) Å · b = 2.9358(11) Å · c = 7.675(3) Å
Cell angles
β = 100.958(17) °
Ratio a:b:c
1 : 0.525 : 1.373
Type-locality form

globular aggregates, up to 1 mm in diameter, sometimes showing µm-sized prismatic crystals of marioantofilliite

Comment

z = 1/3

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
45.98%
29CuCopperCopper463.546254.184
40.58%
13AlAluminiumAluminium226.98253.964
8.62%
1HHydrogenHydrogen181.00818.144
2.90%
6CCarbonCarbon112.01112.011
1.92%
Total626.285100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • IMA2025-012
  • Marioantofilliiet

In other languages

German
IMA 2025-012 · Marioantofilliit

Classification

Strunz
10th ed.

5.DA.50

  • 5CarbonatesClass
  • 5.DCarbonates with additional anions, with H2ODivision
  • 5.DAWith medium-sized cationsGroup
  • 5.DA.50MarioantofilliiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2025Bosi, F.; Hatert, F.; Pasero, M.; Mills, S. J. (2025) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 85. European Journal of Mineralogy, 37 (3). 337-342 doi:10.5194/ejm-37-337-2025DOI: 10.5194/ejm-37-337-2025
  2. 2025Biagioni, C.; Sejkora, J.; Perchiazzi, N.; Mugnaioli, E.; Mauro, D.; Belmonte, D.; Škoda, R.; Dolnı́ček, Z. (2025) Marioantofilliite, [Cu₄Al₂(OH)₁₂](CO₃)·3H₂O, a new member of the hydrotalcite supergroup from Liguria (Italy). European Journal of Mineralogy, 37 (5). 733-746 doi:10.5194/ejm-37-733-2025DOI: 10.5194/ejm-37-733-2025
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Marioantofilliite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/marioantofilliite-472233},
  note      = {Accessed 2026-05-11}
}