Marshite

CuI
IMA status
  • Approved
  • Grandfathered
IMA symbol
Msh
Discovered
1892
Also known as
  • Cuprojodid
  • Kupferjodür
  • Marshiet
  • +2 more

Where it forms, where it's found

Type locality
Broken Hill Proprietary Mine
  1. Broken Hill
  2. Broken Hill district
  3. Yancowinna Co.
  4. New South Wales
  5. Australia

-31.9665°, 141.4643°

18recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine
Transparency
Transparent
Colour
Colorless to pale yellow when fresh · turns pink to dark brownish-red.
Streak
Yellow
Tenacity
brittle
Cleavage
Perfect

(011).

Fracture
Conchoidal · Sub-Conchoidal
Density
5.68 g/cm³

Optical

Optical type
Isotropic
Refractive index
2.35
Surface relief
Very high
Principal indices
nβ 2.35
Pleochroism
Non-pleochroic
UV response
Frequently fluorescent red in both SW and LW
Notes

May exhibit anomalous birefringence.

Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation

Crystallography

Crystal system
Isometric
Space group
#208
Cell parameters
a = 6.05 Å
Z
4
Morphology

Crystals usually tetrahedral, with modifying (001) or other forms; rarely cubo-octahedral through equal development of (001), (111) and (111). (001) and {hhl} striated parallel to the edges with the tetrahedra. Positive and negative tetrahedra exhibit no differences in surface characteristics.

Twinning

On (111), repeated at times.

Comment

Tetrahedral

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
53IIodineIodine1126.904126.904
66.63%
29CuCopperCopper163.54663.546
33.37%
Total190.450100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Cuprojodid
  • Kupferjodür
  • Marshiet
  • Marszyt
  • Native copper iodide

In other languages

German
Cuprojodid · Jodkupfer · Kupferjodür · Marshit
Italian
Marshite

Classification

Strunz
10th ed.

3.AA.05

  • 3HalidesClass
  • 3.ASimple halides, without H2ODivision
  • 3.AAM:X = 1:1, 2:3, 3:5, etc.Group
  • 3.AA.05MarshiteSpecies
Dana
8th ed.

09.01.07.03

  • 09Normal HalidesClass
  • 09.01AXType
  • 09.01.07Nantokite SeriesGroup
  • 09.01.07.03MarshiteSpecies
CIM

8.2.11

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.2Halides of CuGroup
  • 8.2.11MarshiteSpecies

Group, growth & confusion

In the same group
4 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1892Marsh, C.W. (1892) On native copper iodide (marshite) and other minerals from Broken Hill, N. S. Wales. Journal and Proceedings of the Royal Society of New South Wales, 26. 326-332
  2. 1894Miers (1894) Zeitschrift für Kristallographie: 24: 207.
  3. 1901Spencer, L. J. (1901) Marshite, Miersite, and Iodyrite from Broken Hill, New South Wales. Mineralogical Magazine and Journal of the Mineralogical Society, 13 (59) 38-53 doi:10.1180/minmag.1901.013.59.04 DOI: 10.1180/minmag.1901.013.59.04
  4. 1902Prior, G. T. (1902) The Identity of Kilbriekenite with Geocronite : and Analyses of Miersite, Marshite, and Copper-pyrites. Mineralogical Magazine and Journal of the Mineralogical Society, 13 (60) 186-190 doi:10.1180/minmag.1902.13.60.07 DOI: 10.1180/minmag.1902.13.60.07
  5. 1922Aminoff (1922) Geol För. Förh.: 44: 444.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Marshite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/marshite-2580},
  note      = {Accessed 2026-05-11}
}