Chlorargyrite

AgCl
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cag
Discovered
1565
Also known as
  • Argent corné
  • Argent cornea
  • Argent muriaté
  • +41 more

History

Long before anyone called it a mineral, miners had a name for the waxy, translucent crust that lined the upper reaches of silver veins: horn silver. Weathered by dry desert air, the mineral dulls to the look and feel of an animal's horn. It is soft enough to cut with a knife.

The formal name is younger and more literal. It joins the Greek chloros, meaning pale green, to the Latin argentum, silver — a plain description of a pale, silver-bearing chloride.

Earlier centuries reached for stranger words. Alchemists knew silver chloride as luna cornea, which translates as horn silver: luna, the moon, was their codename for the metal. A separate older mineral name, cerargyrite, was used for the same substance before the modern one took hold.

The compound itself was pinned down in 1565. In that year the German scholar Georg Fabricius identified silver chloride as a distinct compound of silver. That recognition long predated its naming as a mineral. The species name came much later: chlorargyrite was first described in 1875, from occurrences in the Broken Hill district of New South Wales, Australia.

Industrial & practical applications

Chlorargyrite has a single use that matters: it is an ore of silver. Where it gathers in quantity, it is a rich one. Soft horn silver gives up its metal far more easily than a stubborn sulfide does.

That richness comes with a catch. Chlorargyrite is a secondary mineral, formed when existing silver deposits weather near the surface. It concentrates in the oxidized zone — the upper, weathered part of a vein, above the water table. There, air and groundwater have altered the original ore. In arid regions, where that zone runs deep and stays dry, the mineral can dominate the workable silver.

So it is a near-surface ore, valuable where it is abundant but seldom the whole of a deposit. The richest example on record is the Bridal Chamber occurrence at Lake Valley, in Sierra County, New Mexico, which is almost pure chlorargyrite. At Chañarcillo in Chile, weathering has replaced the upper ore's native silver and silver sulfide with chlorargyrite and a family of related silver halides.

Below that weathered cap the chloride thins out, and the unaltered sulfide ores take over. Modern silver supply leans on those primary minerals and on silver won as a by-product of other metals. Chlorargyrite is a local, supplementary ore rather than a main source.

Where it forms, where it's found

Geological setting

Oxidized zone of silver deposits, especially in arid regions.

Type locality
Marienberg mining district
  1. Erzgebirgskreis
  2. Saxony
  3. Germany
1,406recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789101.5 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Resinous
Transparency
Transparent · Translucent
Colour
Colourless (fresh) · bright chartreuse-green · light yellow · light green · grey · becoming violet-brown on exposure to light.
Streak
White
Tenacity
sectile
Cleavage
None Observed
Fracture
Irregular/Uneven · Sub-Conchoidal
Density
5.556 g/cm³

Optical

Optical type
Isotropic
Surface relief
Very high
Principal indices
n 2.071
Tropism
Isotropic
UV response
None.
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 2.071

Crystallography

Crystal system
Isometric
Space group
#224
Cell parameters
a = 5.554 Å
Z
4
Morphology

Crystals cubic, with (111) and (011), sometimes large, and the other reported forms as small and rare modifying faces. Often parallel or subparallel groups. Massive; crusts and waxy coatings with drusy surfaces. Wax- or horn-like masses; columnar or stalactitic; rarely fibrous.

Twinning

On (111).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
47AgSilverSilver1107.868107.868
75.26%
17ClChlorineChlorine135.45035.450
24.74%
Total143.318100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • I

Synonyms

  • Argent corné
  • Argent cornea
  • Argent muriaté
  • Argento sulphure et arsenico mineralisatum
  • Argentum cornu pellucido simile
  • Argyroceratit
  • Argyroceratita
  • Argyroceratite
  • Cerargerit
  • Cerargerita
  • Cerargerite
  • Cerargyrit
  • Cerargyrita
  • Cerargyrite
  • Cerargyrites
  • Cherargirio
  • Chlorargyriet
  • Chlorsilber
  • Chlorsilberspath
  • Chlorsilfver
  • Chlorure d'argent
  • Corneous Silver
  • Horn Silver
  • Horn-Silfver
  • Hornerz
  • Hornfarbs-Silber
  • Hornsilber
  • Hornsølv
  • Horny Silver Ore
  • Kerargyre
  • Kerargyrite
  • Kerat
  • Kerate
  • Minera argenti cornea
  • Muriate of Silver
  • Ostwaldit
  • Ostwaldita
  • Ostwaldite
  • Plata cornea
  • Silber-Kerat
  • Silberhornerz
  • Silberhornspath
  • Silberspath
  • Silfverhornmalm

In other languages

French
chlorargyrite
German
Cerargyrit · Chlorargyrit · Hornerz · Hornsilber · Kerargyrit · Silberhornerz
Spanish
argiroceratita · cerargirita · clorargirita · ostwaldita · plata córnea · querargirita
Italian
Chlorargyrite · Clorargirite
Japanese
塩化銀鉱 · 角銀鉱
Chinese
角銀礦
Simplified Chinese
角银矿
Traditional Chinese
角銀礦
Russian
кераргирит · роговое серебро · хлораргирит
Arabic
كلورارجيريت

Classification

Strunz
10th ed.

3.AA.15

  • 3HalidesClass
  • 3.ASimple halides, without H2ODivision
  • 3.AAM:X = 1:1, 2:3, 3:5, etc.Group
  • 3.AA.15ChlorargyriteSpecies
Dana
8th ed.

09.01.04.01

  • 09Normal HalidesClass
  • 09.01AXType
  • 09.01.04Embolite SeriesGroup
  • 09.01.04.01ChlorargyriteSpecies
CIM

8.3.1

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.3Halides of AgGroup
  • 8.3.1ChlorargyriteSpecies

Group, growth & confusion

In the same group
4 members
Often grow together
9 minerals

Literature, links & citation

Citations
  1. 1565Gesner, K. (1565) Argentum cornupellucido simile. in De omni rerum fossilium genere, gemmis, lapidibus, metallis, et huiusmodi, libri aliquot, plerique nunc. Primum Editi, Excudebat Jacobus Gesnerus (Tiguri): 62-62.
  2. 1795Klaproth, M. H. (1795) IX. Untersuchung der Silbererze, Hornerz. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 1. Rottmann. p.125-130.
  3. 1830Beudant, François-Sulpice (1830) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 1 - Tome Premier [Volume One]. Chez Verdière.
  4. 1841Breithaupt, J.F.A. (1841) Cerargyrites chlorus oder Hornsilber. in Vollständiges Handbuch der Mineralogie, Volume 2, Arnoldische Buchhandlung (Dresden and Leipzig): 315-317.
  5. 1875Weisbach, A. (1875) Chlorargyrit. in Synopsis Mineralogica. Systematische Uebersicht des Mineralreiches, J. G. Englehardt’sche (Freiberg): 37-38.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chlorargyrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chlorargyrite-1014},
  note      = {Accessed 2026-05-11}
}