Metaköttigite

(Zn,Fe3+)3(AsO4)2 · 8(H2O,OH)
IMA status
  • Approved
IMA symbol
Mköt
Also known as
  • IMA1979-077
  • Metakoettigit
  • Metakoettigita
  • +2 more

Where it forms, where it's found

Geological setting

Oxide zone of an arsenic-rich polymetallic mineral deposit.

Type locality
Ojuela Mine
  1. Mapimí
  2. Mapimí Municipality
  3. Durango
  4. Mexico

25.7936°, -103.7911°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Translucent
Colour
Bluish-gray
Cleavage
Perfect

(110)

Optical

Optical type
Biaxial (+) · 2V measured = 93° · 2V calc = 90°
Refractive index
1.648 – 1.716
Surface relief
High
Principal indices
nα 1.648 · nβ 1.680 · nγ 1.716
Pleochroism
Strong

X = dark blue, Y = yellow, Z = pale yellow.

Dispersion
r > v
Michel-Lévy diagramhighlighted lineδ = 0.0680
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]680 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation680 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.96(2) Å · b = 9.44(2) Å · c = 4.72(1) Å
Cell angles
α = 95.6(2) ° · β = 97.0(2) ° · γ = 107.8(2) °
Ratio a:b:c
1 : 1.186 : 0.593
Z
1
Twinning

Universal on (110).

Type-locality form

Minute, bluish-gray crystals in oriented intergrowth with kottigite.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
41.66%
30ZnZincZinc365.380196.140
21.28%
26FeIronIron355.845167.535
18.18%
33AsArsenicArsenic274.922149.844
16.26%
1HHydrogenHydrogen241.00824.192
2.62%
Total921.687100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1979-077
  • Metakoettigit
  • Metakoettigita
  • Metakoettigite
  • Metaköttigiet

In other languages

German
IMA 1979-077 · Metaköttigit
Italian
Metaköttigite

Classification

Strunz
10th ed.

8.CE.85

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.85MetaköttigiteSpecies
Dana
8th ed.

40.03.08.02

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.08— unnamed intermediate level —Group
  • 40.03.08.02MetaköttigiteSpecies
CIM

20.3.19

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.3Arsenates of Zn, Cd or HgGroup
  • 20.3.19MetaköttigiteSpecies

Group, growth & confusion

In the same group
2 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1982Schmetzer, K.; Amthauer, G.; Stähle, V.; Medenbach, O. (1982) Metaköttigit, (Zn,Fe3+)(Zn,Fe3+,Fe2+)2(AsO4)2·8(H2O,OH), ein neues Mineral aus Mapimi, Mexiko. Neues Jahrbuch für Mineralogie - Monatshefte, 1982. 506-518
  2. 1983Dunn, P.J.; Grice, J.D.; Fleischer, M.; Pabst, A. (1983) New mineral names. American Mineralogist, 68 (9-10). 1038-1041
  3. 2005(2005) Metaköttigite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Metaköttigite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/metakottigite-2678},
  note      = {Accessed 2026-05-11}
}