Symplesite

Fe2+3(AsO4)2 · 8H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Sym
Discovered
1837
Also known as
  • Symplesiet

Where it forms, where it's found

Geological setting

Oxidised zone of arsenic-bearing hydrothermal deposits.

Type locality
Tännig
  1. Bad Lobenstein
  2. Saale-Orla District
  3. Thuringia
  4. Germany

50.4399°, 11.6745°

84recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Light green · greenish black · light blue · indigo blue
Streak
White, bluish white.
Tenacity
flexible
Cleavage
Perfect

On (110), perfect.

Fracture
Irregular/Uneven
Density
2.96 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 87° · 2V calc = 88°
Refractive index
1.635 – 1.702
Surface relief
High
Principal indices
nα 1.635 · nβ 1.668 · nγ 1.702
Birefringence
0.067
Pleochroism
Strong

X = ┴ <mi>(1_10)</mi> = Deep blue Y = Nearly colourless Z = ^ c 31½° = Pale Yellow

Dispersion
r > v strong
Extinction
Z^c = 31.5° increasing to 50° as oxidised, X perpendicular to {<mi>1-10</mi>
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0670
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]670 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation670 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 4.7505(2) Å · b = 7.7893(5) Å · c = 9.2567(5) Å
Cell angles
α = 106.372(3) ° · β = 93.046(4) ° · γ = 98.152(4) °
Ratio a:b:c
1 : 1.640 : 1.949
Unit cell volume
323.75 ų
Z
1
Morphology

Crystals small and imperfect, elongated [001]; flattened (110) at times. Spherical aggregates with a coarsely fibrous, radial structure.

Twinning

On (110)

Translation gliding
T (110), t[001].
Comment

Runčevski et al. (2015)

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
43.42%
26FeIronIron355.845167.535
28.42%
33AsArsenicArsenic274.922149.844
25.42%
1HHydrogenHydrogen161.00816.128
2.74%
Total589.491100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Symplesiet

In other languages

German
Symplesit
Italian
Simplesite

Classification

Strunz
10th ed.

8.CE.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.45SymplesiteSpecies
Dana
8th ed.

40.03.08.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.08— unnamed intermediate level —Group
  • 40.03.08.01SymplesiteSpecies
CIM

20.9.6

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.9Arsenates of FeGroup
  • 20.9.6SymplesiteSpecies

Group, growth & confusion

In the same group
2 members
Often grow together
5 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1837Breithaupt, August (1837): Bestimmung neuer Mineralien. 1. Symplesischer Diatom oder Symplesit. Journal für praktische Chemie: 10: 501-512.
  2. 1868Bořický (1868): Vh. min. Geselschaft: 3: 98.
  3. 1886Krenner, J.S. (1886) Symplesit Felsőbányáról / Symplesit von Felsö-Banya. Természetrajzi Füzetek: 10: 83-84, 108-109.
  4. 1887Krenner (1887): Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 13: 70.
  5. 1913Tyrell, J.B., Graham, R.P.D. (1913) Yukonite, a new hydrous arsenate of iron and calcium from Tagish Lake, Yukon Territory, Canada; with a note on the associated symplesite. Transactions of the Royal Society of Canada: 7(4): 13-18.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Symplesite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/symplesite-3851},
  note      = {Accessed 2026-05-11}
}