Where it forms, where it's found
- Geological setting
Oxidized veins in a hydrothermal sulfide ore deposit
Oxidized zones of arsenical ores containing zinc.
- Type locality
- Daniel Mine (St. Daniel Mine)
- Neustädtel
- Schneeberg
- Erzgebirgskreis
- Saxony
- Germany
50.5789°, 12.6161°
Varieties
Safety & handling
Physical
- Hardness
- 1Talc
- 2Gypsum
- 3Calcite
- 4Fluorite
- 5Apatite
- 6Orthoclase
- 7Quartz
- 8Topaz
- 9Corundum
- 10Diamond
- Transparency
- Translucent
- Colour
- Should be colorless · but frequently is carmine-red · red-orange · brown · pale grey-blue · grey-green · light rose-pink in transmitted light.
Colored by substituting elements.
- Streak
- Reddish-white to white
- Tenacity
- flexible
- Cleavage
- Perfect
On (010), perfect.
- Fracture
- Fibrous
- Density
- 3.33 g/cm³
Optical
- Optical type
- Biaxial (+) · 2V measured = 74° · 2V calc = 72°
- Refractive index
- 1.622 – 1.671
- Surface relief
- Moderate
- Principal indices
- nα 1.622 · nβ 1.638 · nγ 1.671
- Birefringence
- 0.049
- Pleochroism
- Visible
X, Y = colorless, Z = pale red
- Dispersion
- r > v to r < v strong
- Extinction
- z = b, z ^ c = 37°
- UV response
- not fluorescent
- Notes
Pleochroism should not be present if the mineral is colorless
Crystallography
- Space group
- C2/m
- Cell parameters
- a = 10.24 Å · b = 13.405 Å · c = 4.757 Å
- Cell angles
- β = 105.21 °
- Ratio a:b:c
- 1 : 1.309 : 0.465
- Z
- 2
- Morphology
Crystals prismatic [001] and flattened (010). Massive; crusts with a crystalline surface and fibrous structure.
Chemical composition
Synonyms
- Koettigite
- Köttigiet
- Zinkarseniat
In other languages
- French
- koettigite · köttigite
- German
- Köttigit
- Italian
- Köttigite
Classification
8.CE.40
- 8Phosphates, Arsenates, VanadatesClass
- 8.CPhosphates without additional anions, with H2ODivision
- 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
- 8.CE.40KöttigiteSpecies
40.03.06.05
- 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
- 40.03A3(XO4)2·xH2OType
- 40.03.06Vivianite GroupGroup
- 40.03.06.05KöttigiteSpecies
20.3.6
- 20Arsenates (also arsenates with phosphate, but without other anions)Class
- 20.3Arsenates of Zn, Cd or HgGroup
- 20.3.6KöttigiteSpecies
Group, growth & confusion
AnnabergiteNi3(AsO4)2 · 8H2OMineral—
ArupiteNi3(PO4)2 · 8H2OMineral—
BabánekiteCu3(AsO4)2 · 8H2OMineral—
Barićite(Mg,Fe)3(PO4)2 · 8H2OMineral—
CabreriteNiMg2(AsO4)2·8H2OMineral—
ErythriteCo3(AsO4)2 · 8H2OMineral—- GritsenkoiteCoMg2(AsO4)2(H2O)8Mineral—
HörnesiteMg3(AsO4)2 · 8H2OMineral—
ManganohörnesiteMn2+3(AsO4)2 · 8H2OMineral—- MonteneroiteCu2+Mn2+2(AsO4)2 · 8H2OMineral—
Literature, links & citation
- 1849Köttig (1849) Zinkarseniat (wasserhaltiges) von der Kobaltgrube Daniel bei Schneeberg. Journal für praktische Chemie, Leipzig: 48: 183-186 (as Zinkarseniat).
- 1850Dana, James D. (1850) A System of Mineralogy (3rd ed.) G. P. Putnam. p.711
- 1903de Schulten, A. (1903) Reproduction artificielle de la kœttigite et de l'adamine. Bulletin de la Société française de Minéralogie: 26: 91-94.
- 1940Wolfe, C. W. (1940) Classification of minerals of the type A3(XO4)2·nH2O (concluded) American Mineralogist, 25 (12) 787-809
- 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Köttigite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/kottigite-2263},
note = {Accessed 2026-05-11}
}
