Köttigite

Zn3(AsO4)2 · 8H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Köt
Discovered
1849
Also known as
  • Koettigite
  • Köttigiet
  • Zinkarseniat

Where it forms, where it's found

Geological setting

Oxidized veins in a hydrothermal sulfide ore deposit

Oxidized zones of arsenical ores containing zinc.

Type locality
Daniel Mine (St. Daniel Mine)
  1. Neustädtel
  2. Schneeberg
  3. Erzgebirgskreis
  4. Saxony
  5. Germany

50.5789°, 12.6161°

66recorded occurrences
Source · OpenStreetMap

Varieties

Safety & handling

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Should be colorless · but frequently is carmine-red · red-orange · brown · pale grey-blue · grey-green · light rose-pink in transmitted light.

Colored by substituting elements.

Streak
Reddish-white to white
Tenacity
flexible
Cleavage
Perfect

On (010), perfect.

Fracture
Fibrous
Density
3.33 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 74° · 2V calc = 72°
Refractive index
1.622 – 1.671
Surface relief
Moderate
Principal indices
nα 1.622 · nβ 1.638 · nγ 1.671
Birefringence
0.049
Pleochroism
Visible

X, Y = colorless, Z = pale red

Dispersion
r > v to r < v strong
Extinction
z = b, z ^ c = 37°
UV response
not fluorescent
Notes

Pleochroism should not be present if the mineral is colorless

Michel-Lévy diagramhighlighted lineδ = 0.0490
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]490 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation490 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 10.24 Å · b = 13.405 Å · c = 4.757 Å
Cell angles
β = 105.21 °
Ratio a:b:c
1 : 1.309 : 0.465
Z
2
Morphology

Crystals prismatic [001] and flattened (010). Massive; crusts with a crystalline surface and fibrous structure.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
41.42%
30ZnZincZinc365.380196.140
31.73%
33AsArsenicArsenic274.922149.844
24.24%
1HHydrogenHydrogen161.00816.128
2.61%
Total618.096100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Koettigite
  • Köttigiet
  • Zinkarseniat

In other languages

French
koettigite · köttigite
German
Köttigit
Italian
Köttigite

Classification

Strunz
10th ed.

8.CE.40

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.40KöttigiteSpecies
Dana
8th ed.

40.03.06.05

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.06Vivianite GroupGroup
  • 40.03.06.05KöttigiteSpecies
CIM

20.3.6

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.3Arsenates of Zn, Cd or HgGroup
  • 20.3.6KöttigiteSpecies

Group, growth & confusion

Often grow together
2 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1849Köttig (1849) Zinkarseniat (wasserhaltiges) von der Kobaltgrube Daniel bei Schneeberg. Journal für praktische Chemie, Leipzig: 48: 183-186 (as Zinkarseniat).
  2. 1850Dana, James D. (1850) A System of Mineralogy (3rd ed.) G. P. Putnam. p.711
  3. 1903de Schulten, A. (1903) Reproduction artificielle de la kœttigite et de l'adamine. Bulletin de la Société française de Minéralogie: 26: 91-94.
  4. 1940Wolfe, C. W. (1940) Classification of minerals of the type A3(XO4)2·nH2O (concluded) American Mineralogist, 25 (12) 787-809
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Köttigite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/kottigite-2263},
  note      = {Accessed 2026-05-11}
}