Natrophosphate

Na7(PO4)2F · 19H2O
IMA status
  • Approved
IMA symbol
Nap
Discovered
1972
Also known as
  • IMA1971-041

Where it forms, where it's found

Type locality
Material'naya Adit
  1. Yukspor Mountain
  2. Murmansk Oblast
  3. Russia

67.6406°, 33.7424°

8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · greasy
Colour
White
Streak
White
Cleavage
Imperfect/Fair

octahedral imperfect

Fracture
Conchoidal
Density
1.71 g/cm³

Optical

Optical type
Isotropic
UV response
Pale orange
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation

Crystallography

Crystal system
Isometric
Space group
#221
Cell parameters
a = 27.6241(2) Å
Z
56
Morphology

Rare as octahedra, dodecahedra, or tetrahedra, typically rounded and up to 1 cm in size; also in monomineralic aggregates and veinlets.

Type-locality form

monomineralic aggregates up to 5 cm

Comment

new unit cell parameters from Avdontceva et al. (2021); range observed in previous research: a = 27.79–27.93 A; data for synthetic counterparts: a=28.1150 (RT), a=27.9777 (T=100K)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2715.999431.973
60.65%
11NaSodiumSodium722.990160.930
22.60%
15PPhosphorusPhosphorus230.97461.948
8.70%
1HHydrogenHydrogen381.00838.304
5.38%
9FFluorineFluorine118.99818.998
2.67%
Total712.153100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1971-041

In other languages

German
Natrophosphat
Italian
Natrofosfato · Natrophosphate

Classification

Strunz
10th ed.

8.DN.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DNWith only large cationsGroup
  • 8.DN.05NatrophosphateSpecies
Dana
8th ed.

42.13.09.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.13MiscellaneousType
  • 42.13.09— unnamed intermediate level —Group
  • 42.13.09.01NatrophosphateSpecies
CIM

22.1.3

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.1Phosphates, arsenates or vanadates with fluorideGroup
  • 22.1.3NatrophosphateSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1972Kapustin, Y.L., Bykova, A.V., Bukin, V.I. (1972) Natrophosphate, a new mineral. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 101(1): 80-86.
  2. 1972Kapustin, Yu.L., Bykova, A.V., Bukin, V.I. (1972) Natrophosphate, a new mineral. International Geology Review, 14 (9) 984-989 doi:10.1080/00206817209475790DOI: 10.1080/00206817209475790
  3. 1973Fleischer, Michael (1973) New mineral names. American Mineralogist, 58 (1-2). 139-141
  4. 1974Baur, W. H., Tillmanns, E. (1974) Salt hydrates. X. The crystal structure determinations of heptasodium fluoride bisphosphate 19-hydrate and heptasodium fluoride bisarsenate 19-hydrate and the computer simulation of the isomorphous vanadate salt. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 30 (9) 2218-2224 doi:10.1107/s0567740874006777DOI: 10.1107/s0567740874006777
  5. 1980Khomyakov, A.P., Bykova, A.V. (1980) Natrophosphate - the first occurrence in the Lovozzero alkalic massif. Mineralog. Zhurnal: 2(6): 88-91.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natrophosphate — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natrophosphate-2862},
  note      = {Accessed 2026-05-11}
}