Nahpoite

Na2(PO3OH)
IMA status
  • Approved
IMA symbol
Nhp
Discovered
1981
Also known as
  • IMA1981-002
  • Nahpoiet

Where it forms, where it's found

Geological setting

Veined phosphatic ironstones.

sodalite xenoliths, late-stage phosphatian and halogen alterations in alkalic syenite.

Type locality
Big Fish River
  1. Dawson mining district
  2. Yukon
  3. Canada

68.4738°, -136.4874°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Earthy
Transparency
Translucent · Opaque
Colour
White
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
2.58 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.49 – 1.505
Surface relief
Low
Principal indices
nα 1.490 · nγ 1.505
Birefringence
0.015
Pleochroism
Non-pleochroic
Dispersion
none
Extinction
parallel
UV response
Creamy-white (shortwave), dull-white (longwave)
Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#15
Cell parameters
a = 5.471 Å · b = 6.841 Å · c = 5.451 Å
Cell angles
β = 116.338 °
Ratio a:b:c
1 : 1.250 : 0.996
Z
2
Morphology

Powdery

Type-locality form

Powdery white

Comment

P21/a alternative space group.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
45.08%
11NaSodiumSodium222.99045.980
32.39%
15PPhosphorusPhosphorus130.97430.974
21.82%
1HHydrogenHydrogen11.0081.008
0.71%
Total141.958100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1981-002
  • Nahpoiet

In other languages

German
Nahpoit
Italian
Nahpoite

Classification

Strunz
10th ed.

8.AD.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ADWith only large cationsGroup
  • 8.AD.05NahpoiteSpecies
Dana
8th ed.

37.01.05.01

  • 37Anhydrous Acid Phosphates, Arsenates and VanadatesClass
  • 37.01MiscellaneousType
  • 37.01.05— unnamed intermediate level —Group
  • 37.01.05.01NahpoiteSpecies
CIM

19.1.3

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.3NahpoiteSpecies

Group, growth & confusion

Often grow together
4 minerals

Literature, links & citation

Citations
  1. 1981Coleman, L. C., Robertson, B. T. (1981) Nahpoite Na2HPO4, a new mineral from the Big Fish River area, Yukon Territory. The Canadian Mineralogist, 19 (3) 373-376
  2. 1992Robinson, George W., Van Velthuizen, Jerry, Ansell, H. Gary, Sturman, B. Darko (1992) Mineralogy of the Rapid Creek and Big Fish River Area, Yukon Territory. The Mineralogical Record, 23 (4) 1-47
  3. 1995Baldus, M., Meier, B. H., Ernst, R. R., Kentgens, A. P. M., Meyer zu Altenschildesche, H., Nesper, R. (1995) Structure Investigation on Anhydrous Disodium Hydrogen Phosphate Using Solid-State NMR and X-ray Techniques. Journal Of The American Chemical Society, 117 (18) 5141-5147 doi:10.1021/ja00123a017DOI: 10.1021/ja00123a017
  4. 2005(2005) Nahpoite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Nahpoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/nahpoite-2832},
  note      = {Accessed 2026-05-11}
}