Niahite

(NH4)Mn2+(PO4) · H2O
IMA status
  • Approved
IMA symbol
Nhi
IMA approved
1977
Also known as
  • IMA1977-022
  • Niahiet

Where it forms, where it's found

Geological setting

Limestone cave with bat guano

Type locality
Niah Great Cave (Gunong Jerneb)
  1. Miri Division
  2. Sarawak
  3. Malaysia

3.8244°, 113.7618°

4recorded occurrences
Source · OpenStreetMap

Physical

Colour
Pale orange
Streak
White
Density
2.39 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 54° · 2V calc = 50°
Refractive index
1.582 – 1.609
Surface relief
Moderate
Principal indices
nα 1.582 · nβ 1.604 · nγ 1.609
Dispersion
r < v moderate
Michel-Lévy diagramhighlighted lineδ = 0.0270
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]270 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation270 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#34
Cell parameters
a = 5.68 Å · b = 8.78 Å · c = 4.88 Å
Ratio a:b:c
1 : 1.546 : 0.859
Type-locality form

fine radiating and sub-parallel clusters of crystals up to 0.5mm in size

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
43.02%
25MnManganeseManganese154.93854.938
29.54%
15PPhosphorusPhosphorus130.97430.974
16.66%
7NNitrogenNitrogen114.00714.007
7.53%
1HHydrogenHydrogen61.0086.048
3.25%
Total185.962100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1977-022
  • Niahiet

In other languages

German
IMA 1977-022 · Niahit
Italian
Niahite

Classification

Strunz
10th ed.

8.CH.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CHWith large and medium-sized cations, RO4:H2O < 1:1Group
  • 8.CH.20NiahiteSpecies
Dana
8th ed.

40.01.02.02

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.01AB(XO4)·xH2OType
  • 40.01.02— unnamed intermediate level —Group
  • 40.01.02.02NiahiteSpecies
CIM

19.12.5

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.5NiahiteSpecies

Group, growth & confusion

Often grow together
1 mineral
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1983Bridge, P. J., Robinson, B. W. (1983) Niahite—A new mineral from Malaysia. Mineralogical Magazine, 47 (342) 79-80 doi:10.1180/minmag.1983.047.342.14 DOI: 10.1180/minmag.1983.047.342.14
  2. 1984Dunn, Pete J.; Cabri, Louis J.; Chao, George Y.; Fleischer, Michael; Francis, Carl A.; Grice, Joel D.; Jambor, John L.; Pabst, Adolf (1984) New mineral names. American Mineralogist, 69 (3-4). 406-412
  3. 1995Carling, S.G., Day, P., Visser, D. (1995) Crystal and magnetic structures of layer transition metal phosphate hydrates. Inorganic Chemistry: 34: 3917-3927.
  4. 1995Yakubovich, O.V., Karimova, O.V., Mel'nikov, O.K., Urusov, V.S., (1995) Crystal structure of (NH4)(FePO4)HF - synthetic variant of niahite. Doklady Akademii Nauk SSSR: 342: 40-44.
  5. 2005(2005) Niahite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Niahite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/niahite-2893},
  note      = {Accessed 2026-05-11}
}