Orthowalpurgite

(UO2)Bi4O4(AsO4)2 · 2H2O
IMA status
  • Approved
IMA symbol
Owal
Discovered
1980
IMA approved
1994
Also known as
  • IMA1994-024
  • Orthowalpurgiet
  • Orthowalpurgit
  • +1 more

Where it forms, where it's found

Type locality
Schmiedestollen dump
  1. Wittichen
  2. Schenkenzell
  3. Rottweil
  4. Freiburg Region
  5. Baden-Württemberg
  6. Germany

48.3369°, 8.3414°

1recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine
Transparency
Transparent
Colour
Pale yellow
Streak
Pale yellow
Tenacity
brittle
Cleavage
Poor/Indistinct

an indistinct cleavage parallel to (001)

Fracture
Conchoidal

Optical

Optical type
Biaxial (-) · 2V measured = 70° · 2V calc = 70°
Refractive index
1.91 – 2.05
Surface relief
Very high
Principal indices
nα 1.91 · nβ 2 · nγ 2.05
Pleochroism
Non-pleochroic
Dispersion
r < v
UV response
Non-fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.1400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1400 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1400 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pbcm
Cell parameters
a = 5.492(1) Å · b = 13.324(2) Å · c = 20.685(3) Å
Ratio a:b:c
1 : 2.426 : 3.766
Unit cell volume
1513.6 ų
Z
4
Morphology

Tabular on (010), often elongated parallel to [100]. Forming fan-shaped aggregates. Forms observed: (010), (001), (104) (rare), and (100).

Twinning

None observed on type material

Type-locality form

Transparent yellow crystals uo to 0.3mm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth4208.980835.920
56.34%
8OOxygenOxygen1615.999255.984
17.25%
92UUraniumUranium1238.029238.029
16.04%
33AsArsenicArsenic274.922149.844
10.10%
1HHydrogenHydrogen41.0084.032
0.27%
Total1483.809100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1994-024
  • Orthowalpurgiet
  • Orthowalpurgit
  • Orthowalpurgita

In other languages

German
IMA 1994-024 · Orthowalpurgin
Italian
Orthowalpurgite · Ortowalpurgite

Classification

Strunz
10th ed.

8.EA.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.EUranyl phosphates and arsenatesDivision
  • 8.EAUO2:RO4 = 1:2Group
  • 8.EA.05OrthowalpurgiteSpecies
Dana
8th ed.

40.05.09.02

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.05AXO4·xH2OType
  • 40.05.09Walpurgite GroupGroup
  • 40.05.09.02OrthowalpurgiteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1995Krause, Werner, Effenberger, Herta, Brandstätter, Franz (1995) Orthowalpurgite (UO2)Bi4O4(AsO4)2-2H2O, a new mineral from the Black Forest, Germany. European Journal of Mineralogy, 7 (6) 1313-1324 doi:10.1127/ejm/7/6/1313 DOI: 10.1127/ejm/7/6/1313
  2. 1996Mandarino, Joseph A. (1996) Abstracts of New Mineral Descriptions. The Mineralogical Record, 27 (6) 463-466
  3. 2005(2005) Orthowalpurgite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2005Burns, Peter C. (2005) U6+ minerals and inorganic compounds: insights into an expanded structural hierarchy of crystal structures. The Canadian Mineralogist, 43 (6) 1839-1894 doi:10.2113/gscanmin.43.6.1839 DOI: 10.2113/gscanmin.43.6.1839
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Orthowalpurgite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/orthowalpurgite-3032},
  note      = {Accessed 2026-05-11}
}