Phosphowalpurgite

(UO2)Bi4O4(PO4)2 · 2H2O
IMA status
  • Approved
IMA symbol
Pwal
IMA approved
2001
Also known as
  • IMA2001-062
  • Phosphowalpurgiet
  • Phosphowalpurgit
  • +1 more

Where it forms, where it's found

Geological setting

Hydrothermal ore in a fault zone between a granite body and the surrounding metamorphic rocks (chlorite – white mica phyllites, metamorphosed into two-mica gneisses and massive hornfels with sillimanite, andalusite and garnet). Phosphorus-rich rocks also occur in the complex.

Type locality
Smrkovec
  1. Březová
  2. Sokolov District
  3. Karlovy Vary Region
  4. Czech Republic

49.9728°, 12.8380°

3recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Transparency
Translucent
Colour
Brownish grey
Streak
Light brown
Tenacity
brittle
Cleavage
Perfect

(010)

Fracture
Irregular/Uneven · Conchoidal
Density
6.36 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.9
Surface relief
Very high
Principal indices
nβ 1.9
UV response
Not fluorescent.
Notes

High indices of refraction (1.9–2.0) and moderate to high birefringence (0.05–0.1).

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.060(3) Å · b = 13.238(4) Å · c = 5.464(3) Å
Cell angles
α = 101.22(4) ° · β = 109.93(3) ° · γ = 87.93(4) °
Ratio a:b:c
1 : 1.875 : 0.774
Unit cell volume
470.6 ų
Morphology

Subhedral to euhedral tabular crystals with the (010) form dominant.

Twinning

"Simple twinning".

Type-locality form

Subhedral to euhedral tabular crystals, flattened on (010), up to 1 mm in size (typically 0.1-0.3 mm), randomly growing in crystalline crusts, up to 1 cm2 in size, within small fissures and cavities in the quartz gangue.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth4208.980835.920
59.88%
8OOxygenOxygen1615.999255.984
18.34%
92UUraniumUranium1238.029238.029
17.05%
15PPhosphorusPhosphorus230.97461.948
4.44%
1HHydrogenHydrogen41.0084.032
0.29%
Total1395.913100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2001-062
  • Phosphowalpurgiet
  • Phosphowalpurgit
  • Unnamed (P-analogue of Walpurgite)

In other languages

German
IMA 2001-062 · Phosphowalpurgin
Italian
Fosfowalpurgite · Phosphowalpurgite

Classification

Strunz
10th ed.

8.EA.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.EUranyl phosphates and arsenatesDivision
  • 8.EAUO2:RO4 = 1:2Group
  • 8.EA.05PhosphowalpurgiteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 2004Sejkora, J., Čejka, J., Hloušek, J., Novák, M., Šrein, V. (2004) Phosphowalpurgite, the (PO4)-dominant analogue of walpurgite, from Smrkovec, Slavkovský Les Mountains, Czech Republic. The Canadian Mineralogist, 42 (4) 963-972 doi:10.2113/gscanmin.42.4.963 DOI: 10.2113/gscanmin.42.4.963
  2. 2013(2013) Phosphowalpurgite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phosphowalpurgite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phosphowalpurgite-25692},
  note      = {Accessed 2026-05-11}
}