Walpurgite

Bi4O4(UO2)(AsO4)2 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wpg
Discovered
1871
Also known as
  • Phosphate-walpurgite
  • Walpurgiet
  • Walpurgit
  • +1 more

Where it forms, where it's found

Type locality
Walpurgis Flacher vein
  1. Weißer Hirsch Mine (shaft 3)
  2. Neustädtel
  3. Schneeberg
  4. Erzgebirgskreis
  5. Saxony
  6. Germany

50.5883°, 12.6389°

37recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
yellow · orange-yellow · colourless to light yellow in transmitted light.
Streak
Pale brownish yellow
Cleavage
Perfect

On (010), perfect.

Density
6.59 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 50 – 60° · 2V calc = 54 – 74°
Refractive index
1.871 – 2.05
Surface relief
Very high
Principal indices
nα 1.871 – 1.90 · nβ 1.975 – 2.00 · nγ 2.005 – 2.05
Pleochroism
Weak

X = colorless; Y = Z = very faint greenish yellow.

Dispersion
strong
Michel-Lévy diagramhighlighted lineδ = 0.1420
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1420 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1420 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.135(2) Å · b = 10.426(4) Å · c = 5.494(1) Å
Cell angles
α = 101.47(2) ° · β = 110.82(2) ° · γ = 88.20(2) °
Ratio a:b:c
1 : 1.461 : 0.770
Z
1
Morphology

Crystals lath-like [001] and tabular (010) with an oblique termination. Occurs also as sub-parallel aggregates and radial groups.

Twinning

Twin plane and composition surface (010), common, the twinned aggregates pseudo-monoclinic (resembling gypsum).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth4208.980835.920
56.34%
8OOxygenOxygen1615.999255.984
17.25%
92UUraniumUranium1238.029238.029
16.04%
33AsArsenicArsenic274.922149.844
10.10%
1HHydrogenHydrogen41.0084.032
0.27%
Total1483.809100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Phosphate-walpurgite
  • Walpurgiet
  • Walpurgit
  • Waltherite (of Vogl)

In other languages

German
Walpurgin
Spanish
walpurgina
Italian
walpurgite
Japanese
ワルプルギス石

Classification

Strunz
10th ed.

8.EA.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.EUranyl phosphates and arsenatesDivision
  • 8.EAUO2:RO4 = 1:2Group
  • 8.EA.05WalpurgiteSpecies
Dana
8th ed.

40.05.09.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.05AXO4·xH2OType
  • 40.05.09Walpurgite GroupGroup
  • 40.05.09.01WalpurgiteSpecies
CIM

20.6.6

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.6Arsenates of BiGroup
  • 20.6.6WalpurgiteSpecies

Group, growth & confusion

In the same group
2 members
Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1871Weisbach, A. (1871): Vorläufige Mittheilung [Über Trögerit und Walpurgin].Neues Jahrbuch für Mineralogie, Geologie und Paläontologie, 869-870.
  2. 1873Weisbach A. (1873), Neue Uranerze von Neustädtel bei Schneeberg.- Jahrbuch für das Berg- und Hüttenwesen im Königreiche Sachsen, Abhandlungen, 119-121.
  3. 1873Winkler (1873): Journal für praktische Chemie, Leipzig: 7: 6.
  4. 1873Zepharovich, V.R. von (1873): Mineralogisches Lexicon für das Kaiserthum Oesterreich. vol. 2: 341 (Cites Lindacker in Vogl (1857) relating to Waltherite).
  5. 1877Weisbach, A. (1877) Jahrbuch für das Berg- und Hüttenwesen im Königreiche Sachsen, Abhandlungen, 1.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Walpurgite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/walpurgite-4238},
  note      = {Accessed 2026-05-11}
}