Palygorskite

(Mg,Al)2Si4O10(OH) · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Plg
Discovered
1862
Also known as
  • Attapulgit
  • Attapulgita
  • Attapulgite-Palygorskite
  • +4 more

Where it forms, where it's found

Geological setting

Alteration product of magnesium silicates

Type locality
Second Mine
  1. Popovka River
  2. Palygorskaya Distance of Perm Railways
  3. Perm Krai
  4. Russia
294recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White. grayish · yellowish · gray-green
Cleavage
Distinct/Good

Good on (110)

Tough

Density
2.1 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 30 – 61°
Refractive index
1.522 – 1.548
Surface relief
Moderate
Principal indices
nα 1.522 – 1.528 · nβ 1.53 – 1.546 · nγ 1.533 – 1.548
Pleochroism
Visible

X= pale yellow Y=Z= pale yellow-green

Michel-Lévy diagramhighlighted lineδ = 0.0155
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]155 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation155 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 12.78 Å · b = 17.86 Å · c = 5.24 Å
Cell angles
β = 95.78 °
Ratio a:b:c
1 : 1.397 : 0.410
Z
4
Morphology

Commonly fibrous, tangled mats known as mountain leather. Individual, small crystals are lath-shaped.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1515.999239.985
51.72%
14SiSiliconSilicon428.085112.340
24.21%
13AlAluminiumAluminium226.98253.964
11.63%
12MgMagnesiumMagnesium224.30548.610
10.48%
1HHydrogenHydrogen91.0089.072
1.96%
Total463.971100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • K

Synonyms

  • Attapulgit
  • Attapulgita
  • Attapulgite-Palygorskite
  • Paligorskita
  • Polygorskit
  • Polygorskita
  • Polygorskite

In other languages

French
Attapulgite
German
Palygorskit
Spanish
palygorskita
Italian
palygorskite
Portuguese
Atapulgite · Paligorsquita · paligorsquite
Japanese
パリゴルスカイト · パリゴルスキー石
Chinese
凸凹棒石 · 坡缕石 · 坡缕缟石
Simplified Chinese
坡缕石
Traditional Chinese
坡縷石
Russian
Аттапулгит · Аттапульгит · Палыгорскит
Arabic
باليجورسكيت · باليغورسكايت

Classification

Strunz
10th ed.

9.EE.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EESingle tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bandsGroup
  • 9.EE.20PalygorskiteSpecies
Dana
8th ed.

74.03.1a.01

  • 74Phyllosilicates Modulated LayersClass
  • 74.03Modulated Layers with joined stripsType
  • 74.03.1a— unnamed intermediate level —Group
  • 74.03.1a.01PalygorskiteSpecies
CIM

16.7.6

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.7Aluminosilicates of MgGroup
  • 16.7.6PalygorskiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. Permskiye gubernskiye vedomosti (Perm District Gazette): 26: 127.
  2. Smith, Dorian G. W. and Norem, David (1986) The electron-microprobe analysis of palygorskite. Canadian Mineralogist, 24, 499-511.
  3. 1862von Ssaftschenkow, T. (1862) Paligorskit. Verhandlungen der Kaiserlichen Gesellschaft für die Gesammte Mineralogie zu St. Petersburg 1862: 102-104.
  4. 1962Huggins, C.W., Denny, M.V., Shell, H.R. (1962) Properties of palygorskite, an asbestiform mineral: US Bureau of Mines, Report of Investigaton 6071: 17pp.
  5. 1966Van Olphen, H. (1966) Maya Blue: A Clay-Organic Pigment? Science, 154 (3749). 645-646 doi:10.1126/science.154.3749.645DOI: 10.1126/science.154.3749.645
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Palygorskite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/palygorskite-3072},
  note      = {Accessed 2026-05-11}
}