Pearceite

[Ag9CuS4][(Ag,Cu)6(As,Sb)2S7]
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pea
Discovered
1896
Also known as
  • Pearceiet
  • Pirseite

Where it forms, where it's found

Type locality
Mollie Gibson Mine
  1. Aspen
  2. Aspen Mining District (Roaring Fork Mining District)
  3. Pitkin County
  4. Colorado
  5. USA

39.1917°, -106.8083°

317recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
submetallic
Transparency
Opaque
Colour
Black
Streak
Black
Tenacity
brittle
Cleavage
None Observed

none

Fracture
Conchoidal · Sub-Conchoidal
Density
6.15 g/cm³

Optical

Optical type
Biaxial
Refractive index
2.7
Surface relief
Very high
Principal indices
nα 2.7
Pleochroism
Weak

Very weak in air, fair in oil.

Dispersion
relatively strong
Optical colour
White
Anisotropism
Moderate, typically dark violet.
Internal reflections
Very dark red.
Tropism
Anisotropic
Reflectance R%
(34.8,34.3) 400, (34.2,34.2) 420, (33.4,34.1) 440, (32.5,33.8) 460, (31.5,33.2) 480, (30.6,32.8) 500, (29.8,32.5) 520, (29.3,32.3) 540, (29.0,32.0) 560, (29.0,31.7) 580, (29.1,31.2) 600, (29.1,30.7) 620, (28.9,30.2) 640, (28.6,29.8) 660, (28.0,29.3) 680, (27.4,29.1) 700
Luminescence
No
Reflected-light panel
30.3 %anisotropic · dual curve
Specimen sRGB 195, 136, 81
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Moderate, typically dark violet.
Reflected colour
White
Internal reflections
Very dark red.

Crystallography

Crystal system
Trigonal
Space group
#97
Cell parameters
a = 7.3876 Å · c = 11.8882 Å
Unit cell volume
561.89 ų
Z
1
Type-locality form

Well formed crystals to 3 cm in diameter and 1 cm thick. Most commonly with a hexagonal outline, prominent basal planes (striated) and highly modified edges.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
47AgSilverSilver15107.8681618.020
57.60%
29CuCopperCopper763.546444.822
15.84%
16SSulfurSulfur1132.060352.660
12.56%
51SbAntimonyAntimony2121.760243.520
8.67%
33AsArsenicArsenic274.922149.844
5.33%
Total2808.866100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zn
  • Fe
  • Sb

Synonyms

  • Pearceiet
  • Pirseite

In other languages

French
Pearcéite
German
Pearceit
Spanish
Pearceíta
Italian
Antimonpearceite · Arsenpolibasite · Pearceite · Pearceite-Tac

Classification

Strunz
10th ed.

2.GB.15

  • 2Sulfides and SulfosaltsClass
  • 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
  • 2.GBNeso-sulfarsenites, etc. with additional SGroup
  • 2.GB.15PearceiteSpecies
Dana
8th ed.

03.01.08.01

  • 03SulfosaltsClass
  • 03.01ø > 4Type
  • 03.01.08Pearceite groupGroup
  • 03.01.08.01PearceiteSpecies
CIM

5.2.5

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.2Sulpharsenites etc. of AgGroup
  • 5.2.5PearceiteSpecies

Group, growth & confusion

Often grow together
3 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1829Rose, H. (1829) Ueber die in der natur corkommenden nicht oxydirten verbindungen des antimons und des arseniks. Annalen der Physik und Chemie: 1829: 573-592.
  2. 1833Rose (1833), Ann. Phys.: 28: 158.
  3. 1875Rammelsberg (1875): 123.
  4. 1892Penfield, S.L., Pearce, S.H. (1892) On polybasite and tennantite from the Mollie Gibson Mine in Aspen, Colorado. American Journal of Science: 44: 15-18.
  5. 1896Penfield, S. L. (1896) On Pearceite, a Sulpharsenite of Silver and on the Crystallization of Polybasite. American Journal of Science: 2(7): 17-29.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pearceite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pearceite-3138},
  note      = {Accessed 2026-05-11}
}