Polybasite

[Ag9CuS4][(Ag,Cu)6(Sb,As)2S7]
IMA status
  • Approved
  • Grandfathered
IMA symbol
Plb
Discovered
1829
Also known as
  • Eugenglanz
  • Polibasit
  • Polybasita

Where it forms, where it's found

Geological setting

In low to medium temperature hydrothermal veins

Type locality
Freiberg Mining District
  1. Mittelsachsen
  2. Saxony
  3. Germany
809recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Sub Metallic
Transparency
Opaque
Colour
Black with dark ruby red internal reflections
Streak
Black
Tenacity
very brittle
Cleavage
Imperfect/Fair

Imperfect on (001)

Fracture
Conchoidal
Density
6.1 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 22°
Pleochroism
Weak
Extinction
X = c; Y = a.
Optical colour
Gray white
Anisotropism
Moderate
Internal reflections
Red
Tropism
Anisotropic
Reflectance R%
(33.9,32.5) 400, (33.6,32.8) 420, (33.4,33.0) 440, (33.0,33.9) 460, (32.4,34.0) 480, (31.9,33.8) 500, (31.3,33.4) 520, (30.8,32.8) 540, (30.5,32.2) 560, (30.2,31.7) 580, (29.8,31.1) 600, (29.3,30.5) 620, (29.1,29.3) 640, (27.3,29.1) 660, (27.2,28.4) 680, (26.7,27.8) 700
Luminescence
None
Notes

n>2.72

Reflected-light panel
30.7 %anisotropic · dual curve
Specimen sRGB 195, 140, 81
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Moderate
Reflected colour
Gray white
Internal reflections
Red

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 26.17 Å · b = 15.11 Å · c = 23.89 Å
Cell angles
β = 90 °
Ratio a:b:c
1 : 0.577 : 0.913
Z
16
Morphology

Always in pseudohexagonal trillings, as tablets and rosettes. Some forms include (001), (310), (110), (101) (203) (101) (403), (201), (114), (112), (111), (221), (331), (114), (112), (111).

Twinning

(110)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
47AgSilverSilver15107.8681618.020
57.60%
29CuCopperCopper763.546444.822
15.84%
16SSulfurSulfur1132.060352.660
12.56%
51SbAntimonyAntimony2121.760243.520
8.67%
33AsArsenicArsenic274.922149.844
5.33%
Total2808.866100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • As
  • Fe

Synonyms

  • Eugenglanz
  • Polibasit
  • Polybasita

In other languages

French
Polybasite
German
Eugenglanz · Polybasit · Polybasit-T2ac
Spanish
Polibasita
Italian
Polibasite
Chinese
多基银 · 硫锑铜银矿
Russian
Полибазит

Classification

Strunz
10th ed.

2.GB.15

  • 2Sulfides and SulfosaltsClass
  • 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
  • 2.GBNeso-sulfarsenites, etc. with additional SGroup
  • 2.GB.15PolybasiteSpecies
Dana
8th ed.

03.01.07.02

  • 03SulfosaltsClass
  • 03.01ø > 4Type
  • 03.01.07Polybasite groupGroup
  • 03.01.07.02PolybasiteSpecies
CIM

5.2.12

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.2Sulpharsenites etc. of AgGroup
  • 5.2.12PolybasiteSpecies

Group, growth & confusion

Often grow together
5 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1829Rose, H. (1829) Ueber die in der Natur vorkommenden nicht oxydirten Verbindungen des Antimons und des Arseniks. 2. Polybasit, eine neue Species. Annalen der Physik und Chemie, 15, 573-591.
  2. 1896Penfield, S.L. (1896) On pearceite, a sulpharsenite of silver and on the crystallization of polybasite. American Journal of Science: 2: 17-29.
  3. 1903Mügge (1903) 394, 401.
  4. 1911Van Horn, F.R. (1911) A discussion of the formulas of pearceite and polybasite. American Journal of Science: 32: 40-44.
  5. 1934Gossner, B., Kraus, O. (1934). Über Kristallform und chemische Zusammensetzung von Polybasit. Centralblatt Min., Abt. A, 1-6.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Polybasite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/polybasite-3256},
  note      = {Accessed 2026-05-11}
}