Aguilarite

Ag4SeS
IMA status
  • Approved
  • Grandfathered
IMA symbol
Agu
Discovered
1891
Also known as
  • Aguilaritt

Where it forms, where it's found

Geological setting

An uncommon, relatively low-temperature, mineral in hydrothermal deposits rich in silver and selenium, but manifestly deficient in sulfur.

Type locality
San Carlos Mine
  1. La Luz
  2. Guanajuato Municipality
  3. Guanajuato
  4. Mexico
111recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Bright lead-gray on fresh surfaces

Dull iron black after exposure to air.

Streak
Grey-black
Tenacity
sectile
Cleavage
None Observed
Fracture
Hackly
Density
7.40 g/cm³

Optical

Anisotropism
very weak
Tropism
Anisotropic
Reflectance R%
(34.8, 35.1) 400, (34.7, 35.2) 420, (34.6, 35.2) 440, (34.7, 35.3) 460, (34.8, 35.3) 480, (34.8, 35.4) 500, (34.6, 35.6) 520, (34.1, 35.5) 540, (33.5, 35.2) 560, (32.8, 34.6) 580, (32.1, 33.8) 600, (31.5, 33.9) 620, (31.0, 32.4) 640, (30.6, 31.8) 660, (30.2, 31.4) 680, (30.0, 31.0) 700
Reflected-light panel
33.1 %anisotropic · dual curve
Specimen sRGB 202, 146, 82
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
very weak

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 4.33 Å · b = 7.09 Å · c = 7.76 Å
Ratio a:b:c
1 : 1.637 : 1.792
Z
2
Morphology

In skeletal pseudododecahedral crystals, commonly elongated in the direction of a pseudocubic or pseudo-octahedral edge, to 3 cm; also massive and in intergrowths with acanthite or naumannite.<f></f>

Type-locality form

Skeletal pseudo-dodecahedrons. Often lengthened along one of the crystallographic axes or in the direction of a pseudo-octahedral axis. Crystals to 6 x 10 mm and groups to 15 mm.

Comment

Space group P21/n. Originally assumed to be orthorhombic, with a = 4.33, b = 7.09, c = 7.76 A.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
47AgSilverSilver4107.868431.472
79.53%
34SeSeleniumSelenium178.97178.971
14.56%
16SSulfurSulfur132.06032.060
5.91%
Total542.503100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cu

Synonyms

  • Aguilaritt

In other languages

French
Aguilarite
German
Aguilarit
Spanish
Aguilarita
Italian
aguilarite
Japanese
アギラライト
Chinese
辉硒银矿
Russian
Агвиларит
Arabic
أغيلاريت

Classification

Strunz
10th ed.

2.BA.55

  • 2Sulfides and SulfosaltsClass
  • 2.BMetal Sulfides, M: S > 1: 1 (mainly 2: 1)Division
  • 2.BAWith Cu, Ag, AuGroup
  • 2.BA.55AguilariteSpecies
Dana
8th ed.

02.04.01.03

  • 02SulfidesClass
  • 02.04AmBnXp, with (m+n):p = 2:1Type
  • 02.04.01Acanthite GroupGroup
  • 02.04.01.03AguilariteSpecies
CIM

3.2.4

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.2Sulphides etc. of AgGroup
  • 3.2.4AguilariteSpecies

Group, growth & confusion

In the same group
2 members
Often grow together
10 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1891Genth, F.A. (1891) Aguilarite, a new species. American Journal of Science: 41: 401-402.
  2. 1892Genth, F.A. (1892) Aguilarite. American Journal of Science: 44: 381-383.
  3. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  4. 1969Ramdohr, Paul (1969) The Ore Minerals and their Intergrowths. Pergamon Press, Oxford. 1174pp. doi:10.1016/c2013-0-10027-xDOI: 10.1016/c2013-0-10027-x
  5. 1972Main, J. V., Rodgers, K. A., Kobe, H. W., Woods, C. P. (1972) Aguilarite from the Camoola Reef, Maratoto Valley, New Zealand. Mineralogical Magazine, 38 (300) 961-964 doi:10.1180/minmag.1972.038.300.07 DOI: 10.1180/minmag.1972.038.300.07
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Aguilarite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/aguilarite-59},
  note      = {Accessed 2026-05-11}
}