Pentahydrite

Mg(SO4) · 5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Phy
Discovered
1951
Also known as
  • Allenit
  • Allenita
  • Allenite
  • +4 more

Where it forms, where it's found

Type locality
Cripple Creek Mining District
  1. Teller County
  2. Colorado
  3. USA

38.7467°, -105.1783°

39recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Colourless · pale blue

pale blue or pale green from impurities.

Streak
White
Density
1.896 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 55° · 2V calc = 34°
Refractive index
1.482 – 1.518
Surface relief
Moderate
Principal indices
nα 1.482 – 1.495 · nβ 1.492 – 1.512 · nγ 1.493 – 1.518
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0170
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]170 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation170 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 6.314(5) Å · b = 10.505(18) Å · c = 6.030(6) Å
Cell angles
α = 81.17 ° · β = 109.88 ° · γ = 105.1 °
Ratio a:b:c
1 : 1.664 : 0.955
Z
2
Morphology

Typically as efflorescences.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
68.43%
16SSulfurSulfur132.06032.060
15.23%
12MgMagnesiumMagnesium124.30524.305
11.55%
1HHydrogenHydrogen101.00810.080
4.79%
Total210.436100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Allenit
  • Allenita
  • Allenite
  • Epsomite (of Hobbs)
  • Magnesium Chalcanthite
  • Pentahydriet
  • Pentahydrita

In other languages

French
Pentahydrite
German
Pentahydrit
Italian
pentahydrite · Pentaidrite

Classification

Strunz
10th ed.

7.CB.20

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CBWith only medium-sized cationsGroup
  • 7.CB.20PentahydriteSpecies
Dana
8th ed.

29.06.07.03

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.06AXO4·xH2OType
  • 29.06.07Chalchanthite Group (Triclinic: P-1)Group
  • 29.06.07.03PentahydriteSpecies
CIM

25.3.4

  • 25SulphatesClass
  • 25.3Sulphates of MgGroup
  • 25.3.4PentahydriteSpecies

Group, growth & confusion

In the same group
4 members
Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1905Hobbs, W.H. (1905) Contributions from the Mineralogical Laboratory of the University of Wisconsin. American Geologist, Minneapolis (1888-1905): 36: 179-184 (184). (as epsomite)
  2. 1908Keller, H.F. (1908) Notes on Some Chilean Copper Minerals. Proceedings of the American Philosophical Society: 47: 79-85 (81). (as double sulphate of copper and magnesium)
  3. 1908Keller (1908) Proceedings of the American Philosophical Society: 47: 81 (as Double Sulphate of Copper and Magnesium).
  4. 1927Allen, E.T., Day, A.L. (1927) Steam Wells and Other Thermal Activity at "The Geysers", California. Carnegie Institute Washington Publication: 378: 106 pgs (42).
  5. 1927Robson, Homer Louis (1927) The system MgSO4·H2O from 68 to 240°. Journal Of The American Chemical Society, 49 (11). 2772-2783 doi:10.1021/ja01410a016DOI: 10.1021/ja01410a016
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pentahydrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pentahydrite-3153},
  note      = {Accessed 2026-05-11}
}