Chalcanthite

Cu(SO4) · 5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cct
Discovered
1853
Also known as
  • Blue Stone
  • Blue Vitriol
  • Chalcanthit
  • +21 more

Where it forms, where it's found

Geological setting

Found in the oxidized zones of copper deposits, usually in arid regions where it is not dissolved by ground water. Commonly associated with other hydrated sulphates of Cu or Fe.

Type locality
Chuquicamata Mine
  1. Chuquicamata District
  2. Calama
  3. El Loa Province
  4. Antofagasta
  5. Chile

-22.2894°, -68.9011°

886recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous (Glassy)
Transparency
Transparent · Translucent
Colour
Green · green blue · light blue · or dark blue · colourless to pale blue in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Imperfect/Fair

Imperfect on (110), Indistinct on (111); and, (110) in traces.

Fracture
Conchoidal
Density
2.286 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 56° · 2V calc = 56°
Refractive index
1.514 – 1.543
Surface relief
Moderate
Principal indices
nα 1.514 · nβ 1.537 · nγ 1.543
Dispersion
r < v
Luminescence
None
Michel-Lévy diagramhighlighted lineδ = 0.0290
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]290 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation290 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 6.11 Å · b = 10.673 Å · c = 5.95 Å
Cell angles
α = 97.58 ° · β = 107.17 ° · γ = 77.55 °
Ratio a:b:c
1 : 1.747 : 0.974
Z
2
Morphology

Crystal short prismatic (001) or less commonly tabular (111). Natural crystals rather rare. Commonly found as stalactic material, massive, granular filling veins (cross-fiber veinlets) and as crusts.

Twinning

Rarely forms cruciform twins, with the edges [001] and [100] on one crystal respectively parallel to [100] and [001] on the other, and with (010) in common.

Parting
None reported.
Comment

Non-standard unit cell.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
57.67%
29CuCopperCopper163.54663.546
25.45%
16SSulfurSulfur132.06032.060
12.84%
1HHydrogenHydrogen101.00810.080
4.04%
Total249.677100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Mg
  • Co

Synonyms

  • Blue Stone
  • Blue Vitriol
  • Chalcanthit
  • Chalcanthita
  • Chalcanthum
  • Chalcantita
  • Chalkanthita
  • Chalkanthite
  • Copper vitriol
  • Couperouse Bleue
  • Cuivre Sulfaté
  • Cyanose
  • Cyanosit
  • Cyanosita
  • Cyanosite
  • Cyprian vitriol
  • Kupferchalcanthit
  • Kupfervitriol
  • Sulphate of Copper
  • Vitriolo azul
  • Vitriolo di Rame
  • Vitriolum cupri
  • Vitriolum Cypri
  • Vitriolum veneris

In other languages

French
Calcantite · Calchante · Chacalcanthite · Chalcanthite · Chalcantite · Chalkanthite · Couperouse bleue · Cuivre sulfaté · Cyanosite · Cyprian vitriol
German
Chalkanthit
Spanish
calcantita · calclasa · chalcantita · chalclasa
Italian
Calcantite
Portuguese
Calcantita · calcantite · Caparrosa-azul · Vitríolo-azul
Japanese
胆礬
Chinese
胆矾
Russian
Халькантит · Цианозит
Arabic
كبريتات نحاس مميأة · كلكنتيت

Classification

Strunz
10th ed.

7.CB.20

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CBWith only medium-sized cationsGroup
  • 7.CB.20ChalcanthiteSpecies
Dana
8th ed.

29.06.07.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.06AXO4·xH2OType
  • 29.06.07Chalchanthite Group (Triclinic: P-1)Group
  • 29.06.07.01ChalcanthiteSpecies
CIM

25.2.3

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.3ChalcanthiteSpecies

Group, growth & confusion

In the same group
4 members
Often grow together
3 minerals

Literature, links & citation

Citations
  1. Dioscorides, P., [Translated by Cornarius J, 1557] (70) Chalcantum. in De materia medica Libri V., Froben (Basileae): 451-453.
  2. Zeitschrift für Kristallographie: 192: 1-53.
  3. 1826Kupffer, A.F. (1826) Ueber die Krystallisation des Kupfervitriols, nebst allgemeinen Betrachtungen über das ein- und eingliedrige oder tetartoprismatische System. Annalen der Physik: 84: 215-230 (217).
  4. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  5. 1853von Kobell, Franz [Franz Wolffgang Kobel] (1853) Die Mineral-Namen und die mineralogische Nomenklatur. J.G. Cotta'schen Buchhandlung.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chalcanthite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chalcanthite-959},
  note      = {Accessed 2026-05-11}
}