Philrothite

TlAs3S5
IMA status
  • Approved
IMA symbol
Phr
IMA approved
2013
Also known as
  • IMA2013-066
  • Philrothiet

Where it forms, where it's found

Type locality
Lengenbach Quarry
  1. Fäld
  2. Binn
  3. Goms
  4. Valais
  5. Switzerland

46.3653°, 8.2205°

2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Streak
Dark brown streak
Tenacity
brittle
Density
4.635 g/cm³

Optical

Pleochroism
Weak

Weakly pleochroic from dark grey to light grey

Anisotropism
Grey to bluish rotation tints (Under crossed polars)
Tropism
Anisotropic
Reflectance R%
(26.5,28.8) 471, (25.4,27.2) 548, (24.6,26.3) 586, (24.0,25.1) 652
Reflected-light panel
25.1 %anisotropic · dual curve
Specimen sRGB 180, 128, 72
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Grey to bluish rotation tints (Under crossed polars)

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 8.013(2) Å · b = 24.829(4) Å · c = 11.762(3) Å
Cell angles
β = 132.84(2) °
Ratio a:b:c
1 : 3.099 : 1.468
Unit cell volume
1715.9 ų
Z
8
Type-locality form

Crystals up to 200 μm across on realgar

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic374.922224.766
38.13%
81TlThalliumThallium1204.380204.380
34.67%
16SSulfurSulfur532.060160.300
27.20%
Total589.446100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2013-066
  • Philrothiet

In other languages

German
IMA 2013-066 · Philrothit
Italian
philrothite

Classification

Strunz
10th ed.

2.HC.05f

  • 2Sulfides and SulfosaltsClass
  • 2.HSulfosalts of SnS archetypeDivision
  • 2.HCWith only PbGroup
  • 2.HC.05fPhilrothiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1925Canneri, C. and Fernandes, F. (1925): Atti Accad. Lincei, Roma, l, 671. [synth. TlAs3S5]
  2. 2014Bindi, L., Nestola, F., Makovicky, E., Guastoni, A., De Battisti, L. (2014) Tl-bearing sulfosalt from the Lengenbach quarry, Binn Valley, Switzerland: Philrothite, TlAs3S5. Mineralogical Magazine, 78 (1) 1-9 doi:10.1180/minmag.2014.078.1.01 DOI: 10.1180/minmag.2014.078.1.01
  3. 2015(2015) Philrothite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Philrothite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/philrothite-44003},
  note      = {Accessed 2026-05-11}
}