Pierrotite

Tl2(Sb,As)10S16
IMA status
  • Approved
IMA symbol
Pie
Discovered
1969
IMA approved
1969
Also known as
  • IMA1969-036
  • Pierrotiet

Where it forms, where it's found

Geological setting

Hydrothermal deposit in limestone.

Type locality
Jas Roux
  1. La Chapelle-en-Valgaudemar
  2. Gap
  3. Hautes-Alpes
  4. Provence-Alpes-Côte d'Azur
  5. France

44.8125°, 6.3217°

4recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Grayish black
Streak
Red-brown
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven · Sub-Conchoidal
Density
4.97 g/cm³

Optical

Optical colour
white
Anisotropism
moderate
Internal reflections
red
Tropism
Anisotropic
Reflectance R%
(35.9,39.6) 400, (35.2,38.8) 420, (34.5,38.0) 440, (33.7,37.2) 460, (33.1,36.6) 480, (32.5,36.0) 500, (31.9,35.5) 520, (31.3,35.0) 540, (30.7,34.5) 560, (30.2,34.0) 580, (29.7,33.4) 600, (29.1,32.8) 620, (28.6,32.1) 640, (28.0,31.5) 660, (27.4,30.9) 680, (26.7,30.3) 700
UV response
Not fluorescent
Reflected-light panel
31.2 %anisotropic · dual curve
Specimen sRGB 195, 140, 82
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
moderate
Reflected colour
white
Internal reflections
red

Crystallography

Crystal system
Orthorhombic
Space group
Pna21
Cell parameters
a = 8.77 Å · b = 38.8 Å · c = 8.03 Å
Ratio a:b:c
1 : 4.424 : 0.916
Z
4
Type-locality form

Gray black laths and polycrystalline aggregates.

Comment

Axes are in a new setting; old transformation abc -> bac

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
51SbAntimonyAntimony10121.7601217.600
42.15%
33AsArsenicArsenic1074.922749.220
25.94%
16SSulfurSulfur1632.060512.960
17.76%
81TlThalliumThallium2204.380408.760
14.15%
Total2888.540100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1969-036
  • Pierrotiet

In other languages

German
IMA 1969-036 · Pierrotit
Italian
Pierrotite

Classification

Strunz
10th ed.

2.HC.05f

  • 2Sulfides and SulfosaltsClass
  • 2.HSulfosalts of SnS archetypeDivision
  • 2.HCWith only PbGroup
  • 2.HC.05fPierrotiteSpecies
Dana
8th ed.

03.08.07.01

  • 03SulfosaltsClass
  • 03.081 < ø < 2Type
  • 03.08.07— unnamed intermediate level —Group
  • 03.08.07.01PierrotiteSpecies
CIM

5.5.17

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.5Sulpharsenites etc. of TlGroup
  • 5.5.17PierrotiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1970Guillemin, Claude, Johan, Zdenek, Laforêt, Claude, Picot, Paul (1970) La pierrotite Tl2(Sb,As)10 S17, une nouvelle espèce minérale. Bulletin de Minéralogie, 93 (1) 66-71 doi:10.3406/bulmi.1970.6429 DOI: 10.3406/bulmi.1970.6429
  2. 1972Fleischer, M. (1972) New Mineral Names. American Mineralogist, 57 (11-12). 1909-1914
  3. 1983Engel, P., Gostojić, M., Nowacki, W. (1983) The crystal structure of pierrotite, Tl2(Sb,As)10S16. Zeitschrift für Kristallographie, 165, 209-215.
  4. 1985Dunn, Pete J., Chao, George Y., Fleischer, Michael, Ferraiolo, James A., Langley, Richard H., Pabst, Adolf, Zilczer, Janet A. (1985) New mineral names. American Mineralogist, 70 (1-2) 214-221
  5. 2005(2005) Pierrotite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pierrotite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pierrotite-3209},
  note      = {Accessed 2026-05-11}
}