Pitiglianoite

K2Na6(Si6Al6)O24(SO4) · 2H2O
IMA status
  • Approved
IMA symbol
Pgl
IMA approved
1990
Also known as
  • IMA1990-012
  • Pitiglianoiet

Where it forms, where it's found

Geological setting

Metasomatized blocks of volcanic ejecta.

Type locality
Case Collina
  1. Pitigliano
  2. Grosseto Province
  3. Tuscany
  4. Italy

42.6425°, 11.7303°

9recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless
Streak
White
Tenacity
brittle
Cleavage
Poor/Indistinct
Fracture
Sub-Conchoidal
Density
2.37 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.506 – 1.508
Surface relief
Moderate
Principal indices
nω 1.508 · nε 1.506
Michel-Lévy diagramhighlighted lineδ = 0.0020
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]20 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation20 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#104
Cell parameters
a = 22.121(3) Å · c = 5.221(1) Å
Z
3
Type-locality form

Hexagonal prisms up to 4 mm long and 1 mm in diameter.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3015.999479.970
45.17%
14SiSiliconSilicon628.085168.510
15.86%
13AlAluminiumAluminium626.982161.892
15.23%
11NaSodiumSodium622.990137.940
12.98%
19KPotassiumPotassium239.09878.196
7.36%
16SSulfurSulfur132.06032.060
3.02%
1HHydrogenHydrogen41.0084.032
0.38%
Total1062.600100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1990-012
  • Pitiglianoiet

In other languages

German
IMA 1990-012 · Pitiglianoit
Italian
Pitiglianoite

Classification

Strunz
10th ed.

9.FB.05

  • 9SilicatesClass
  • 9.FTektosilicates without zeolitic H2ODivision
  • 9.FBTektosilicates with additional anionsGroup
  • 9.FB.05PitiglianoiteSpecies
Dana
8th ed.

76.02.05.11

  • 76Tectosilicates Al-si FrameworkClass
  • 76.02Al-Si Framework Feldspathoids and related speciesType
  • 76.02.05Cancrinite groupGroup
  • 76.02.05.11PitiglianoiteSpecies
CIM

17.10.2

  • 17Silicates Containing other AnionsClass
  • 17.10Silicates with sulphate, molybdate or tungstateGroup
  • 17.10.2PitiglianoiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1991Merlino, Stefano, Mellini, Marcello, Bonaccorsi, Elena, Pasero, Marco, Leoni, Leonardo, Orlandi, Paolo (1991) Pitiglianoite, a new feldspathoid from southern Tuscany, Italy: Chemical composition and crystal structure. American Mineralogist, 76 (11-12) 2003-2008
  2. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  3. 2001(2001) Pitiglianoite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2006Ventura, Giancarlo Della, Bellatreccia, Fabio, Bonaccorsi, Elena (2006) CO2 in minerals of the cancrinite-sodalite group: pitiglianoite. European Journal of Mineralogy, 17 (6) 847-851 doi:10.1127/0935-1221/2005/0017-0847DOI: 10.1127/0935-1221/2005/0017-0847
  5. 2007Bonaccorsi, Elena, Ventura, Giancarlo Della, Bellatreccia, Fabio, Merlino, Stefano (2007) The thermal behaviour and dehydration of pitiglianoite, a mineral of the cancrinite-group. Microporous and Mesoporous Materials, 99 (3). 225-235 doi:10.1016/j.micromeso.2006.09.040DOI: 10.1016/j.micromeso.2006.09.040
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pitiglianoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pitiglianoite-3223},
  note      = {Accessed 2026-05-11}
}