Rotherkopfite

KNa2Fe2+(Fe2+)2(Ti1.5Fe2+0.5)[Si4O12]2
IMA status
  • Approved
IMA symbol
Rkp
IMA approved
2023
Also known as
  • Rotherkopfiet

Where it forms, where it's found

Geological setting

cavities in a xenolith embedded in a vesicular alkaline basalt. presumed to have formed as the result of contact metasomatism of the xenolith by the alkaline basalt melt.

Type locality
Rother Kopf
  1. Roth
  2. Gerolstein
  3. Gerolstein
  4. Vulkaneifel
  5. Rhineland-Palatinate
  6. Germany

50.2453°, 6.6214°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
dark brownish red
Streak
light orange
Tenacity
brittle
Cleavage
None Observed

fracture curved

Fracture
Conchoidal
Density
3.20 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 53.2° · 2V calc = 53.1°
Refractive index
1.668 – 1.72
Surface relief
High
Principal indices
nα 1.668 · nβ 1.678 · nγ 1.720
Pleochroism
Non-pleochroic
UV response
No fluorescence was observed in either long- or short-wave ultraviolet illumination
Michel-Lévy diagramhighlighted lineδ = 0.0520
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]520 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation520 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 16.460(2) Å · b = 12.5457(6) Å · c = 10.0487(7) Å
Cell angles
β = 115.669(7) °
Ratio a:b:c
1 : 0.762 : 0.610
Z
4
Twinning

none observed

Type-locality form

equant to tabular crystals up to about 0.2 mm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
39.96%
14SiSiliconSilicon828.085224.680
23.38%
26FeIronIron3.555.845195.457
20.34%
22TiTitaniumTitanium1.547.86771.800
7.47%
11NaSodiumSodium222.99045.980
4.78%
19KPotassiumPotassium139.09839.098
4.07%
Total960.992100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Rotherkopfiet

In other languages

German
Rotherkopfit

Classification

Strunz
10th ed.

9.EH.05

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EHTransitional structures between phyllosilicate and other silicate unitsGroup
  • 9.EH.05RotherkopfiteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 2024Kampf, A. R., Möhn, G., Ma, C., Rossman, G. R., Désor, J., Guan, Y. (2024) Rotherkopfite, KNa₂(Fe²⁺2.5Ti⁴⁺1.5)Fe²⁺(Si₄O₁₂)₂, a new neptunite-group mineral without essential lithium, from Rother Kopf, Eifel volcanic fields, Germany. European Journal of Mineralogy, 36 (4). 605-614 doi:10.5194/ejm-36-605-2024DOI: 10.5194/ejm-36-605-2024
  2. 2024Bosi, Ferdinando, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2024) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 77. European Journal of Mineralogy, 36 (1). 165-172 doi:10.5194/ejm-36-165-2024DOI: 10.5194/ejm-36-165-2024
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Rotherkopfite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/rotherkopfite-471009},
  note      = {Accessed 2026-05-11}
}