Roxbyite

Cu9S5
IMA status
  • Approved
IMA symbol
Rox
Discovered
1986
IMA approved
1986
Also known as
  • IMA1986-010
  • Roxbyiet

Where it forms, where it's found

Geological setting

Stratabound bornite-chalcopyrite-pyrite mineralization and djurleite-bornite-roxbyite lenses and cross cutting veins.

Type locality
Olympic Dam Mine
  1. Olympic Dam
  2. Pastoral Unincorporated Area
  3. South Australia
  4. Australia

-30.4400°, 136.8728°

35recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Blue-black to black
Cleavage
Poor/Indistinct

(100)

Fracture
Irregular/Uneven · Step-Like

Optical

UV response
Not fluorescent in UV

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 13.4051(9) Å · b = 13.4090(8) Å · c = 15.4852(3) Å
Cell angles
α = 90.022(2) ° · β = 90.021(2) ° · γ = 90.020(2) °
Ratio a:b:c
1 : 1.000 : 1.155
Z
2
Morphology

As single crystals, to 0.01 mm, epitaxially intergrown with djurleite; in powdery mixtures with djurleite.

Type-locality form

Mixture with djurleite. Small single crystals with dimensions up to 0.01 mm.

Comment

Pseudo-monoclinic, with pseudo-space group C2/m, Cm or C2, and a = 53.79, b = 30.90, c = 13.36 Å, beta = 90°. Type material is complexly twinned in six sectors.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper963.546571.914
78.11%
16SSulfurSulfur532.060160.300
21.89%
Total732.214100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe

Synonyms

  • IMA1986-010
  • Roxbyiet

In other languages

German
IMA 1986-010 · Roxbyit
Italian
Roxbyite

Classification

Strunz
10th ed.

2.BA.05

  • 2Sulfides and SulfosaltsClass
  • 2.BMetal Sulfides, M: S > 1: 1 (mainly 2: 1)Division
  • 2.BAWith Cu, Ag, AuGroup
  • 2.BA.05RoxbyiteSpecies
Dana
8th ed.

02.04.07.04

  • 02SulfidesClass
  • 02.04AmBnXp, with (m+n):p = 2:1Type
  • 02.04.07Chalcocite Group ([Cu]2-x S] formulae)Group
  • 02.04.07.04RoxbyiteSpecies
CIM

3.1.5

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.1Sulphides etc. of CuGroup
  • 3.1.5RoxbyiteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 1988Mumme, W. G., Sparrow, G. J., Walker, G. S. (1988) Roxbyite, a New Copper Sulphide Mineral from the Olympic Dam Deposit, Roxby Downs, South Australia. Mineralogical Magazine, 52 (366) 323-330 doi:10.1180/minmag.1988.052.366.03DOI: 10.1180/minmag.1988.052.366.03
  2. 1989Jambor, John L., Vanko, David A. (1989) New mineral names. American Mineralogist, 74 (7-8) 946-951
  3. 2005(2005) Roxbyite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2012Mumme, W. G., Gable, R. W., Petricek, V. (2012) The crystal structure of roxbyite, Cu58S32. The Canadian Mineralogist, 50 (2) 423-430 doi:10.3749/canmin.50.2.423 DOI: 10.3749/canmin.50.2.423
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Roxbyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/roxbyite-3468},
  note      = {Accessed 2026-05-11}
}