Digenite

Cu1.8S
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dg
Discovered
1844
Also known as
  • Alpha chalcocite
  • Blauer Chalkosin
  • Blue Chalcocite
  • +14 more

Where it forms, where it's found

Geological setting

Hydrothermal copper deposits - both as primary and secondary mineral, mafic intrusives, exhalation product, pegmatites.

Type locality
Copper slate deposits
  1. Sangerhausen
  2. Mansfeld-Südharz
  3. Saxony-Anhalt
  4. Germany
1,145recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Grey to greyish black · turning bluish on exposure to air
Streak
Greyish black
Tenacity
brittle
Cleavage
Distinct/Good

(111) on synthetic material

Fracture
Conchoidal
Density
5.546 g/cm³

Optical

Optical colour
Bluish grey
Anisotropism
Mostly isotropic.
Tropism
Anisotropic
Reflectance R%
(29.6) 400, (28.8) 420, (28.0) 440, (27.0) 460, (25.9) 480, (24.8) 500, (23.5) 520, (22.2) 540, (21.0) 560, (19.9) 580, (18.9) 600, (18.0) 620, (17.2) 640, (16.3) 660, (15.5) 680, (14.8) 700
UV response
Not fluorescent in UV
Reflected-light panel
22.0 %isotropic · single curve
Specimen sRGB 156, 120, 76
White reference100 % reflector under same lamp
Anisotropism
Mostly isotropic.
Reflected colour
Bluish grey

Crystallography

Crystal system
Trigonal
Space group
R-3 2/m
Cell parameters
a = 3.919 Å · c = 48.00 Å
Z
3
Morphology

Pseudocubic crystals (rare) to 3 cm, usually as intergrowths with other copper sulphides. At temperatures below 81°C, digenite is trigonal R3m; above that temperature, digenite is isometric.

Comment

Above 73°C, cubic with space group <i>Fm</i>-3<i>m</i>, <i>a</i> = 5.57 Å, Z = 4.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper1.863.546114.383
78.11%
16SSulfurSulfur132.06032.060
21.89%
Total146.443100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe

Synonyms

  • Alpha chalcocite
  • Blauer Chalkosin
  • Blue Chalcocite
  • Carmenit
  • Carmenita
  • Carmenite
  • Digeniet
  • Diginite
  • Isometric Chalcocite
  • Kupferglanz-α
  • Neodigenit
  • Neodigenita
  • Neodigenite
  • α-Chalcocita
  • α-Chalcocite
  • α-Chalcosit
  • α-Chalkosin

In other languages

French
digénite
German
Digenit
Spanish
Digenita
Italian
Digenite
Japanese
方輝銅鉱
Chinese
蓝辉铜矿
Simplified Chinese
蓝辉铜矿
Traditional Chinese
藍輝銅礦
Arabic
ديغينيت

Classification

Strunz
10th ed.

2.BA.10

  • 2Sulfides and SulfosaltsClass
  • 2.BMetal Sulfides, M: S > 1: 1 (mainly 2: 1)Division
  • 2.BAWith Cu, Ag, AuGroup
  • 2.BA.10DigeniteSpecies
Dana
8th ed.

02.04.07.03

  • 02SulfidesClass
  • 02.04AmBnXp, with (m+n):p = 2:1Type
  • 02.04.07Chalcocite Group ([Cu]2-x S] formulae)Group
  • 02.04.07.03DigeniteSpecies
CIM

3.1.3

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.1Sulphides etc. of CuGroup
  • 3.1.3DigeniteSpecies

Group, growth & confusion

In the same group
4 members
Often grow together
8 minerals

Literature, links & citation

Citations
  1. 1844Breithaupt, August (1844) Zwei neue Kupfer enthaltende Mineralien aus der Ordnung der Glanze. Annalen der Physik und Chemie, 137. 671-675 doi:10.1002/andp.18441370409DOI: 10.1002/andp.18441370409
  2. 1942Buerger, Newton W. (1942) X-ray evidence for the existence of the mineral digenite, Cu9S5. American Mineralogist, 27 (10) 712-716
  3. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  4. 1958Dormay, Gabrielle, Donnay, J. D. H., Kullerud, G. (1958) Crystal and twin structure of digenite, Cu9S5. American Mineralogist, 43 (3-4) 228-242
  5. 1963Morimoto, N., Kullerud, G. (1963) Polymorphism in digenite. American Mineralogist, 48 (1-2) 110-123
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Digenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/digenite-1291},
  note      = {Accessed 2026-05-11}
}