Where it forms, where it's found
- Geological setting
Hydrothermal copper deposits - both as primary and secondary mineral, mafic intrusives, exhalation product, pegmatites.
- Type locality
- Copper slate deposits
- Sangerhausen
- Mansfeld-Südharz
- Saxony-Anhalt
- Germany
Physical
Optical
- Optical colour
- Bluish grey
- Anisotropism
- Mostly isotropic.
- Tropism
- Anisotropic
- Reflectance R%
- (29.6) 400, (28.8) 420, (28.0) 440, (27.0) 460, (25.9) 480, (24.8) 500, (23.5) 520, (22.2) 540, (21.0) 560, (19.9) 580, (18.9) 600, (18.0) 620, (17.2) 640, (16.3) 660, (15.5) 680, (14.8) 700
- UV response
- Not fluorescent in UV
Crystallography
- Space group
- R-3 2/m
- Cell parameters
- a = 3.919 Å · c = 48.00 Å
- Z
- 3
- Morphology
Pseudocubic crystals (rare) to 3 cm, usually as intergrowths with other copper sulphides. At temperatures below 81°C, digenite is trigonal R3m; above that temperature, digenite is isometric.
- Comment
Above 73°C, cubic with space group <i>Fm</i>-3<i>m</i>, <i>a</i> = 5.57 Å, Z = 4.
Chemical composition
Synonyms
- Alpha chalcocite
- Blauer Chalkosin
- Blue Chalcocite
- Carmenit
- Carmenita
- Carmenite
- Digeniet
- Diginite
- Isometric Chalcocite
- Kupferglanz-α
- Neodigenit
- Neodigenita
- Neodigenite
- α-Chalcocita
- α-Chalcocite
- α-Chalcosit
- α-Chalkosin
In other languages
- French
- digénite
- German
- Digenit
- Spanish
- Digenita
- Italian
- Digenite
- Japanese
- 方輝銅鉱
- Chinese
- 蓝辉铜矿
- Simplified Chinese
- 蓝辉铜矿
- Traditional Chinese
- 藍輝銅礦
- Arabic
- ديغينيت
Classification
2.BA.10
- 2Sulfides and SulfosaltsClass
- 2.BMetal Sulfides, M: S > 1: 1 (mainly 2: 1)Division
- 2.BAWith Cu, Ag, AuGroup
- 2.BA.10DigeniteSpecies
02.04.07.03
- 02SulfidesClass
- 02.04AmBnXp, with (m+n):p = 2:1Type
- 02.04.07Chalcocite Group ([Cu]2-x S] formulae)Group
- 02.04.07.03DigeniteSpecies
3.1.3
- 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
- 3.1Sulphides etc. of CuGroup
- 3.1.3DigeniteSpecies
Group, growth & confusion
Literature, links & citation
- 1844Breithaupt, August (1844) Zwei neue Kupfer enthaltende Mineralien aus der Ordnung der Glanze. Annalen der Physik und Chemie, 137. 671-675 doi:10.1002/andp.18441370409DOI: 10.1002/andp.18441370409
- 1942Buerger, Newton W. (1942) X-ray evidence for the existence of the mineral digenite, Cu9S5. American Mineralogist, 27 (10) 712-716
- 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
- 1958Dormay, Gabrielle, Donnay, J. D. H., Kullerud, G. (1958) Crystal and twin structure of digenite, Cu9S5. American Mineralogist, 43 (3-4) 228-242
- 1963Morimoto, N., Kullerud, G. (1963) Polymorphism in digenite. American Mineralogist, 48 (1-2) 110-123
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Digenite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/digenite-1291},
note = {Accessed 2026-05-11}
}







