Simmonsite

Na2LiAlF6
IMA status
  • Approved
IMA symbol
Sim
Discovered
1992
IMA approved
1999
Also known as
  • IMA1997-045
  • Simmonsiet

Where it forms, where it's found

Geological setting

Aluminofluoride pods (to 20 cm) in amazonite-rich granite pegmatite.

Type locality
Zapot Pegmatite
  1. Gillis Range
  2. Fitting Mining District
  3. Mineral County
  4. Nevada
  5. USA

38.6389°, -118.4817°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Greasy
Transparency
Translucent
Colour
Cloudy white · Cream white · pale buff
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.05 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.359
Surface relief
Low
Principal indices
nα 1.359 · nβ 1.359 · nγ 1.359
Birefringence
0.0009
Pleochroism
Non-pleochroic
Dispersion
r < v weak
Extinction
Nearly isotropic
UV response
Fluoresces moderately bright orange in Short Wave UV, but the fluorescent response may be patchy due to alterations. May be associated with cryolithionite which fluoresces white to pale creamy white in both Short Wave and Long Wave.
Michel-Lévy diagramhighlighted lineδ = 0.0009
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]9 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation9 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 7.5006 Å · b = 7.474 Å · c = 7.503 Å
Cell angles
β = 90.848 °
Ratio a:b:c
1 : 0.996 : 1.000
Z
4
Morphology

Crystals not observed.

Twinning

Abundant polysynthetic twinning.

Type-locality form

Low luster waxy masses.

Comment

space group P21 or P21/m

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine618.998113.988
58.79%
11NaSodiumSodium222.99045.980
23.71%
13AlAluminiumAluminium126.98226.982
13.92%
3LiLithiumLithium16.9406.940
3.58%
Total193.890100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1997-045
  • Simmonsiet

In other languages

German
IMA 1997-045 · Simmonsit
Italian
Simmonsite

Classification

Strunz
10th ed.

3.CB.15

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CBNeso-aluminofluoridesGroup
  • 3.CB.15SimmonsiteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1999Foord, Eugene E., O'Connor, Joseph T., Hughes, John M., Sutley, Stephen J., Falster, Alexander U., Soregaroli, Arthur E., Lichte, Frederick E., Kile, Daniel E. (1999) Simmonsite, Na2LiAlF6, a new mineral from the Zapot amazonite-topaz-zinnwaldite pegmatite, Hawthorne, Nevada, U.S.A. American Mineralogist, 84 (5) 769-772 doi:10.2138/am-1999-5-609 DOI: 10.2138/am-1999-5-609
  2. 2003Ross, Kirk C., Mitchell, Roger H., Chakhmouradian, Anton R. (2003) The crystal structure of synthetic simmonsite, Na2LiAlF6. Journal of Solid State Chemistry, 172. 95-101 doi:10.1016/s0022-4596(02)00137-8DOI: 10.1016/s0022-4596(02)00137-8
  3. 2021(2021) Simmonsite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Simmonsite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/simmonsite-7297},
  note      = {Accessed 2026-05-11}
}