Smythite

(Fe,Ni)3+xS4 (x ≈ 0-0.3)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Syt
Discovered
1956
Also known as
  • Smythiet

Where it forms, where it's found

Geological setting

Inclusions in calcite crystals in quartz geodes in limestone.

Type locality
State Route 37 road cut (6)
  1. Bloomington
  2. Monroe County
  3. Indiana
  4. USA

39.2067°, -86.5536°

75recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
brownish black · bronze-yellow

Black with tinge of brown against a white surface; bronze yellow reflections from {0001}

Streak
dark gray
Tenacity
brittle
Cleavage
Perfect

{0001)

Flexible and elastic in thin lamellae

Fracture
Sub-Conchoidal
Density
4.32 g/cm³

Optical

Pleochroism
Strong

Greyish yellow to reddish brown

Anisotropism
Strong with yellow and blue-grey interference colors
Tropism
Anisotropic
UV response
Not fluorescent.
Notes

Tends to be free of inclusions or intergrowths; strongly resembles pyrrhotite

Crystallography

Crystal system
Trigonal
Space group
#99
Cell parameters
a = 3.465 Å · c = 34.34 Å
Z
3
Morphology

Thin pseudohexagonal plates [0001] and "a rhombohedron". Crystals are so thin at the type locality than the prism was not observed. Twinning common producing warped hexagonal plates. Impossible to visually distinguish at the type locality, and nearby locations, from pyrrhotite with which it is constantly associated (Erd et al., 1957).

Type-locality form

Minute flakes in calcite

Comment

Also given as 3.47, 34.50 A. Z=1 (ICDD 25-1182)

Crystal structure

Synonyms

  • Smythiet

In other languages

German
Smythit
Italian
Smythite

Classification

Strunz
10th ed.

2.CC.10

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CCWith Ni, Fe, Co, PGE, etc.Group
  • 2.CC.10SmythiteSpecies
Dana
8th ed.

02.08.10.02

  • 02SulfidesClass
  • 02.08AmXp, with m:p = 1:1Type
  • 02.08.10— unnamed intermediate level —Group
  • 02.08.10.02SmythiteSpecies
CIM

3.9.7

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.9Sulphides etc. of FeGroup
  • 3.9.7SmythiteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1956Erd, R. C., Evans, H. T. (1956) The compound Fe3S4 (smythite) found in nature. Journal Of The American Chemical Society, 78 (9) 2017 doi:10.1021/ja01590a071DOI: 10.1021/ja01590a071
  2. 1957Erd, Richard C., Evans, Howard T., Richter, and Donald H. (1957) Smythite, a new iron sulfide, and associated pyrrhotite from Indiana. American Mineralogist, 42 (5-6) 309-333
  3. 1970Taylor, Lawrence A. (1970) Smythite, Fe3+xS4 and associated minerals from the Silverfields Mine, Cobalt, Ontario. American Mineralogist, 55 (9-10) 1650-1658
  4. 1972Taylor, Lawrence A., Williams, K. L. (1972) Smythite, (Fe,Ni)9S11 - A redefinition. American Mineralogist, 57 (11-12) 1571-1577
  5. 1972Nickel, E. H. (1972) Nickeliferous smythite from some Canadian occurrences. The Canadian Mineralogist, 11 (2) 514-519
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Smythite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/smythite-3691},
  note      = {Accessed 2026-05-11}
}