Where it forms, where it's found
- Geological setting
Inclusions in calcite crystals in quartz geodes in limestone.
- Type locality
- State Route 37 road cut (6)
- Bloomington
- Monroe County
- Indiana
- USA
39.2067°, -86.5536°
Physical
- Hardness
- 1Talc
- 2Gypsum
- 3Calcite
- 4Fluorite
- 5Apatite
- 6Orthoclase
- 7Quartz
- 8Topaz
- 9Corundum
- 10Diamond
- Transparency
- Opaque
- Colour
- brownish black · bronze-yellow
Black with tinge of brown against a white surface; bronze yellow reflections from {0001}
- Streak
- dark gray
- Tenacity
- brittle
- Cleavage
- Perfect
{0001)
Flexible and elastic in thin lamellae
- Fracture
- Sub-Conchoidal
- Density
- 4.32 g/cm³
Optical
- Pleochroism
- Strong
Greyish yellow to reddish brown
- Anisotropism
- Strong with yellow and blue-grey interference colors
- Tropism
- Anisotropic
- UV response
- Not fluorescent.
- Notes
Tends to be free of inclusions or intergrowths; strongly resembles pyrrhotite
Crystallography
- Space group
- #99
- Cell parameters
- a = 3.465 Å · c = 34.34 Å
- Z
- 3
- Morphology
Thin pseudohexagonal plates [0001] and "a rhombohedron". Crystals are so thin at the type locality than the prism was not observed. Twinning common producing warped hexagonal plates. Impossible to visually distinguish at the type locality, and nearby locations, from pyrrhotite with which it is constantly associated (Erd et al., 1957).
- Type-locality form
Minute flakes in calcite
- Comment
Also given as 3.47, 34.50 A. Z=1 (ICDD 25-1182)
Synonyms
- Smythiet
In other languages
- German
- Smythit
- Italian
- Smythite
Classification
2.CC.10
- 2Sulfides and SulfosaltsClass
- 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
- 2.CCWith Ni, Fe, Co, PGE, etc.Group
- 2.CC.10SmythiteSpecies
02.08.10.02
- 02SulfidesClass
- 02.08AmXp, with m:p = 1:1Type
- 02.08.10— unnamed intermediate level —Group
- 02.08.10.02SmythiteSpecies
3.9.7
- 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
- 3.9Sulphides etc. of FeGroup
- 3.9.7SmythiteSpecies
Group, growth & confusion
Literature, links & citation
- 1956Erd, R. C., Evans, H. T. (1956) The compound Fe3S4 (smythite) found in nature. Journal Of The American Chemical Society, 78 (9) 2017 doi:10.1021/ja01590a071DOI: 10.1021/ja01590a071
- 1957Erd, Richard C., Evans, Howard T., Richter, and Donald H. (1957) Smythite, a new iron sulfide, and associated pyrrhotite from Indiana. American Mineralogist, 42 (5-6) 309-333
- 1970Taylor, Lawrence A. (1970) Smythite, Fe3+xS4 and associated minerals from the Silverfields Mine, Cobalt, Ontario. American Mineralogist, 55 (9-10) 1650-1658
- 1972Taylor, Lawrence A., Williams, K. L. (1972) Smythite, (Fe,Ni)9S11 - A redefinition. American Mineralogist, 57 (11-12) 1571-1577
- 1972Nickel, E. H. (1972) Nickeliferous smythite from some Canadian occurrences. The Canadian Mineralogist, 11 (2) 514-519
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Smythite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/smythite-3691},
note = {Accessed 2026-05-11}
}
