Starkeyite

Mg(SO4) · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ske
Also known as
  • Leonhardtit
  • Leonhardtite
  • Starkeyiet

Where it forms, where it's found

Geological setting

Dump material from a pyrite deposit in dolomite.

A secondary mineral sometimes found in the oxidized zone of sulfide mineral deposits, resulting from the decomposition of pyrite and marcasite. May form from the dehydration of hexahydrite (Chou, 2005).

Type locality
Starkey Mine
  1. Madison County
  2. Missouri
  3. USA

37.4831°, -90.1955°

71recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Dull
Transparency
Translucent · Opaque
Colour
White to very pale yellow or pale greenish white.
Streak
White
Tenacity
brittle
Fracture
Irregular/Uneven
Density
2 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 50° · 2V calc = 46°
Refractive index
1.49 – 1.497
Surface relief
Low
Principal indices
nα 1.490 · nβ 1.491 · nγ 1.497
Birefringence
0.007
Pleochroism
Non-pleochroic
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0070
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]70 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation70 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 5.92 Å · b = 13.6 Å · c = 7.91 Å
Cell angles
β = 90.85 °
Ratio a:b:c
1 : 2.297 : 1.336
Z
4
Morphology

Forms not reported, typically found as powdery efflorescences.

Twinning

Not reported.

Type-locality form

Dull white powdery efflorescence.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
66.52%
16SSulfurSulfur132.06032.060
16.66%
12MgMagnesiumMagnesium124.30524.305
12.63%
1HHydrogenHydrogen81.0088.064
4.19%
Total192.421100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Leonhardtit
  • Leonhardtite
  • Starkeyiet

In other languages

French
Starkeyite
German
IMA 1970-014a · Leonhardtit · Starkeyit
Italian
starkeyite

Classification

Strunz
10th ed.

7.CB.15

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CBWith only medium-sized cationsGroup
  • 7.CB.15StarkeyiteSpecies
Dana
8th ed.

29.06.06.02

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.06AXO4·xH2OType
  • 29.06.06Rozenite Group (Monoclinic)Group
  • 29.06.06.02StarkeyiteSpecies
CIM

25.3.3

  • 25SulphatesClass
  • 25.3Sulphates of MgGroup
  • 25.3.3StarkeyiteSpecies

Group, growth & confusion

In the same group
5 members
Often grow together
4 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1927Robson, Homer Louis (1927) The system MgSO4·H2O from 68 to 240°. Journal Of The American Chemical Society, 49 (11). 2772-2783 doi:10.1021/ja01410a016DOI: 10.1021/ja01410a016
  2. 1945Grawe, O.R. (1945) Pyrite deposits of Missouri. Starkeyite [FeSO4·H2O], a new mineral. Missouri Geological Survey and Water Resources, ser. 2: 30: 209-210.
  3. 1952Berdesinski, W. (1952) Sanderit, Leonhardtit, Allenit und Hexahydrit, neue Mineralien der marinen Kalisalzlagerstätten. Neues Jahrbuch für Mineralogie, Monatshefte, 1952, 28-29.
  4. 1956Grawe, Oliver R. (1956) Strakeyite, a correction. American Mineralogist, 41 (7-8) 662
  5. 1957Fleischer, M. (1957) New mineral names. American Mineralogist, 42 (5-6). 440-444
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Starkeyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/starkeyite-3752},
  note      = {Accessed 2026-05-11}
}