Where it forms, where it's found
- Geological setting
Veinlets cutting manganese ore.
- Type locality
- Molinello Mine
- Ne
- Genoa
- Liguria
- Italy
44.3453°, 9.4589°
Safety & handling
Physical
- Transparency
- Transparent · Translucent
- Colour
- Orange · brownish orange
- Cleavage
- Distinct/Good
Good on (100).
- Density
- 3.84 g/cm³
Optical
- Optical type
- Biaxial (+) · 2V measured = 38 – 46° · 2V calc = 80°
- Refractive index
- 1.745 – 1.76
- Surface relief
- High
- Principal indices
- nα 1.745 · nβ 1.751 · nγ 1.760
- Pleochroism
- Not Visible
- Dispersion
- strong
- Notes
a ≃ α, b = β, c ≃ γ. The angle between a and the cleavage pole is 5-6°. Elongation is positive.
Crystallography
- Cell parameters
- a = 6.6702(2) Å · b = 19.9336(7) Å · c = 7.5759(2) Å
- Cell angles
- β = 95.518(1) °
- Ratio a:b:c
- 1 : 2.988 : 1.136
- Z
- 4
- Twinning
Visible under the microscope. Symmetric, with the twin plane coincident with the cleavage plane.
- Parting
- Distinct parting, normal to elongation.
- Epitaxy
(010)[001]tir // (010)[100]rho (Roth & Meisser, 2011)
- Type-locality form
Small orange grains enclosed in brownish to orange veinlets, about one millimeter thick, cutting a black Mn ore made up mainly of quartz and braunite. The grains never show as idiomorphic crystals. They are typically <0.4 mm but rarely 1.5 mm. They are
- Comment
Space group P21/n. Nagashima et al. (2010) give a = 6.6783(1), b = 19.9075(3), c = 7.5750(1) Å, β = 95.475(1)°. The lower c value in the latter is also confirmed by SXRD studies of samples from Austria (Uwe Kolitsch, unpubl. data). also see Callegari 2020
Chemical composition
- Impurities
- Ti
- Al
- V
- Fe
- Ca
- Na
- K
Synonyms
- IMA1969-061
- Tiragalloiet
In other languages
- German
- IMA 1979-061 · Tiragalloit
- Italian
- Tiragalloite
- Chinese
- 硅砷锰石
Classification
9.BJ.25
- 9SilicatesClass
- 9.BSorosilicatesDivision
- 9.BJSorosilicates with Si3O10, Si4O11, etc. anions; cations in octahedral [6] and greater coordinationGroup
- 9.BJ.25TiragalloiteSpecies
57.02.01.01
- 57Sorosilicates Si3o10 Groups and Larger Noncyclic GroupsClass
- 57.02Insular Si3O10 and Larger Noncyclic Groups with [Si4O13] groupsType
- 57.02.01— unnamed intermediate level —Group
- 57.02.01.01TiragalloiteSpecies
17.7.7
- 17Silicates Containing other AnionsClass
- 17.7Silicates with vanadate, arsenate or antimonateGroup
- 17.7.7TiragalloiteSpecies
Group, growth & confusion
Literature, links & citation
- 1979Gramaccioli, C.M., Griffin, W.L., Mottana, A. (1979) Dati preliminari su un probabile nuovo minerale nella miniera di Molinello (Genova). Rendiconti della Società Italiana di Mineralogia e Petrologia, 35 (1), 145-149.
- 1979Gramaccioli, C. M., Pilati, T., Liborio, G. (1979) Structure of a manganese(II) arsenatotrisilicate, Mn4[AsSi3O12(OH)]: the presence of a new tetrapolyphosphate-like anion. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 35 (10) 2287-2291 doi:10.1107/s0567740879009158DOI: 10.1107/s0567740879009158
- 1980Gramaccioli, Carlo Maria, Griffin, William L., Mottana, Annibale (1980) Tiragalloite, Mn4[AsSi3O12(OH)], a new mineral and the first example of arsenatotrisilicate. American Mineralogist, 65 (9-10) 947-952
- 2001(2001) Tiragalloite. Handbook of Mineralogy. Mineralogical Society of America
- 2010Nagashima, M., Armbruster, T. (2010) Ardennite, tiragalloite and medaite: structural control of (As5+,V5+,Si4+)O4 tetrahedra in silicates. Mineralogical Magazine, 74 (1) 55-71 doi:10.1180/minmag.2010.074.1.55DOI: 10.1180/minmag.2010.074.1.55
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Tiragalloite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/tiragalloite-3974},
note = {Accessed 2026-05-11}
}
