Tiragalloite

Mn2+4As5+Si3O12(OH)
IMA status
  • Approved
IMA symbol
Tga
Discovered
1969
IMA approved
1979
Also known as
  • IMA1969-061
  • Tiragalloiet

Where it forms, where it's found

Geological setting

Veinlets cutting manganese ore.

Type locality
Molinello Mine
  1. Ne
  2. Genoa
  3. Liguria
  4. Italy

44.3453°, 9.4589°

19recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent · Translucent
Colour
Orange · brownish orange
Cleavage
Distinct/Good

Good on (100).

Density
3.84 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 38 – 46° · 2V calc = 80°
Refractive index
1.745 – 1.76
Surface relief
High
Principal indices
nα 1.745 · nβ 1.751 · nγ 1.760
Pleochroism
Not Visible
Dispersion
strong
Notes

a ≃ α, b = β, c ≃ γ. The angle between a and the cleavage pole is 5-6°. Elongation is positive.

Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 6.6702(2) Å · b = 19.9336(7) Å · c = 7.5759(2) Å
Cell angles
β = 95.518(1) °
Ratio a:b:c
1 : 2.988 : 1.136
Z
4
Twinning

Visible under the microscope. Symmetric, with the twin plane coincident with the cleavage plane.

Parting
Distinct parting, normal to elongation.
Epitaxy

(010)[001]tir // (010)[100]rho (Roth & Meisser, 2011)

Type-locality form

Small orange grains enclosed in brownish to orange veinlets, about one millimeter thick, cutting a black Mn ore made up mainly of quartz and braunite. The grains never show as idiomorphic crystals. They are typically <0.4 mm but rarely 1.5 mm. They are

Comment

Space group P21/n. Nagashima et al. (2010) give a = 6.6783(1), b = 19.9075(3), c = 7.5750(1) Å, β = 95.475(1)°. The lower c value in the latter is also confirmed by SXRD studies of samples from Austria (Uwe Kolitsch, unpubl. data). also see Callegari 2020

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese454.938219.752
37.38%
8OOxygenOxygen1315.999207.987
35.38%
14SiSiliconSilicon328.08584.255
14.33%
33AsArsenicArsenic174.92274.922
12.74%
1HHydrogenHydrogen11.0081.008
0.17%
Total587.924100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Al
  • V
  • Fe
  • Ca
  • Na
  • K

Synonyms

  • IMA1969-061
  • Tiragalloiet

In other languages

German
IMA 1979-061 · Tiragalloit
Italian
Tiragalloite
Chinese
硅砷锰石

Classification

Strunz
10th ed.

9.BJ.25

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BJSorosilicates with Si3O10, Si4O11, etc. anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BJ.25TiragalloiteSpecies
Dana
8th ed.

57.02.01.01

  • 57Sorosilicates Si3o10 Groups and Larger Noncyclic GroupsClass
  • 57.02Insular Si3O10 and Larger Noncyclic Groups with [Si4O13] groupsType
  • 57.02.01— unnamed intermediate level —Group
  • 57.02.01.01TiragalloiteSpecies
CIM

17.7.7

  • 17Silicates Containing other AnionsClass
  • 17.7Silicates with vanadate, arsenate or antimonateGroup
  • 17.7.7TiragalloiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1979Gramaccioli, C.M., Griffin, W.L., Mottana, A. (1979) Dati preliminari su un probabile nuovo minerale nella miniera di Molinello (Genova). Rendiconti della Società Italiana di Mineralogia e Petrologia, 35 (1), 145-149.
  2. 1979Gramaccioli, C. M., Pilati, T., Liborio, G. (1979) Structure of a manganese(II) arsenatotrisilicate, Mn4[AsSi3O12(OH)]: the presence of a new tetrapolyphosphate-like anion. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 35 (10) 2287-2291 doi:10.1107/s0567740879009158DOI: 10.1107/s0567740879009158
  3. 1980Gramaccioli, Carlo Maria, Griffin, William L., Mottana, Annibale (1980) Tiragalloite, Mn4[AsSi3O12(OH)], a new mineral and the first example of arsenatotrisilicate. American Mineralogist, 65 (9-10) 947-952
  4. 2001(2001) Tiragalloite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2010Nagashima, M., Armbruster, T. (2010) Ardennite, tiragalloite and medaite: structural control of (As5+,V5+,Si4+)O4 tetrahedra in silicates. Mineralogical Magazine, 74 (1) 55-71 doi:10.1180/minmag.2010.074.1.55DOI: 10.1180/minmag.2010.074.1.55
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tiragalloite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tiragalloite-3974},
  note      = {Accessed 2026-05-11}
}