Tounkite

(Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O
IMA status
  • Approved
IMA symbol
Tou
Discovered
1990
IMA approved
1990
Also known as
  • IMA1990-009
  • Tounkiet

Where it forms, where it's found

Type locality
Malo-Bystrinskoe lazurite deposit
  1. Malaya Bystraya River Valley
  2. Slyudyanka
  3. Russia

51.6219°, 103.4119°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Green to yellowish-green · glass-green with a yellowish or gray tint

The observed differences in the colors are associated with the different amounts of polysulfide groups contained in them. Both samples contain different amounts S52− anions, which are a yellow chromophore, and minor admixtures of the S3− radical anions, which are a very strong blue chromophore, Sample 2 contains significant amounts of S4 molecules (a weak red chromophore) and Sample 3 contains S2− radical anions (a yellow chromophore). Thus, the blue color of Sample 2 is mainly related to the presence of S3− and S4, whereas the green color of Sample 3 is due to the combination of S3−, S2− and S52−.

Streak
White
Cleavage
Distinct/Good

(1010), fair.

Density
2.557 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.528 – 1.543
Surface relief
Moderate
Principal indices
nω 1.528 · nε 1.543
Pleochroism
Visible

O = colorless; E = yellow-green.

Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#119
Cell parameters
a = 12.843(3) Å · c = 32.239(8) Å
Z
6
Twinning

Polysynthetic twinning is a specific feature of tounkite. The boundaries of twin components, connected by a rotation of 180° around the [001] axis, run perpendicular to this axis, along the planes of the six-membered rings. A large 10-layed cage formed at the border between twin components, connected by a rotation of 180° around the [001] axis, which may host the large S52− anion

Type-locality form

elongated crystals, to 1 cm.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen32.515.999519.967
29.40%
20CaCalciumCalcium840.078320.624
18.13%
19KPotassiumPotassium839.098312.784
17.69%
11NaSodiumSodium822.990183.920
10.40%
14SiSiliconSilicon628.085168.510
9.53%
13AlAluminiumAluminium626.982161.892
9.16%
16SSulfurSulfur232.06064.120
3.63%
17ClChlorineChlorine135.45035.450
2.00%
1HHydrogenHydrogen11.0081.008
0.06%
Total1768.276100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1990-009
  • Tounkiet

In other languages

German
IMA 1990-009 · Tounkit
Italian
Tounkite

Classification

Strunz
10th ed.

9.FB.05

  • 9SilicatesClass
  • 9.FTektosilicates without zeolitic H2ODivision
  • 9.FBTektosilicates with additional anionsGroup
  • 9.FB.05TounkiteSpecies
Dana
8th ed.

76.02.05.14

  • 76Tectosilicates Al-si FrameworkClass
  • 76.02Al-Si Framework Feldspathoids and related speciesType
  • 76.02.05Cancrinite groupGroup
  • 76.02.05.14TounkiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1979Leoni, L., Mellini, M., Merlino, S., Orlandi, P. (1979) Cancrinite-like minerals: new data and crystal chemical considerations. Rendiconti della Società Italiana di Mineralogia e Petrologia: 35: 713-719.
  2. 1984Hassan, I., Grundy, H. D. (1984) The crystal structures of sodalite-group minerals. Acta Crystallographica Section B Structural Science, 40 (1) 6-13 doi:10.1107/s0108768184001683DOI: 10.1107/s0108768184001683
  3. 1992Ivanov, V.G., Sapozhnikov, A.N., Piskunova, L.F., Kashayev, A.A. (1992) Tounkite (Na,Ca,K)8(Al6Si6O24)(SO4)2Cl·H2O- a new cancrinite-like mineral. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 121(2): 92-95.
  4. 1994Jambor, John L., Grew, Edward S. (1994) New Mineral Names. American Mineralogist, 79 (1-2) 185-189
  5. 1996Ballirano, P., Maras, A., Buseck, P. R. (1996) Crystal chemistry and IR spectroscopy of Cl- and SO4-bearing cancrinite-like minerals. American Mineralogist, 81 (7) 1003-1012 doi:10.2138/am-1996-7-822 DOI: 10.2138/am-1996-7-822
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tounkite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tounkite-4002},
  note      = {Accessed 2026-05-11}
}