Twinnite

Pb(Sb0.63As0.37)2S4
IMA status
  • Approved
IMA symbol
Twi
Discovered
1966
IMA approved
1966
Also known as
  • IMA1966-017
  • Twinniet

Where it forms, where it's found

Type locality
Taylor Pit
  1. Madoc
  2. Centre Hastings Municipality
  3. Hastings County
  4. Ontario
  5. Canada

44.5022°, -77.4664°

30recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black
Streak
Brownish black
Tenacity
brittle
Cleavage
Perfect

(001)

Density
5.323 g/cm³

Optical

Pleochroism
Strong

displays twin lamellae

Optical colour
white
Tropism
Anisotropic
Reflectance R%
(39.1,45.2) 400, (38.2,44.7) 420, (37.3,44.2) 440, (36.6,43.7) 460, (36.2,43.2) 480, (35.8,42.9) 500, (35.5,42.5) 520, (35.0,42.0) 540, (34.4,41.4) 560, (34.0,40.8) 580, (33.5,40.0) 600, (33.2,39.4) 620, (32.8,38.7) 640, (32.3,38.1) 660, (31.7,37.5) 680, (31.0,37.0) 700
Reflected-light panel
34.8 %anisotropic · dual curve
Specimen sRGB 207, 148, 85
White reference100 % reflector under same lamp
R₁ R₂
Mode
Reflected colour
white

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 7.997(2) Å · b = 19.517(5) Å · c = 8.634(2) Å
Cell angles
β = 91.061(4) °
Ratio a:b:c
1 : 2.441 : 1.080
Z
8
Twinning

Polysynthetic, with composition plane parallel to (100).

Type-locality form

Two megascopic grains, the larger about 1.5 mm in diameter, and four microscopic grains.

Comment

Space group P21/n. Originally assumed to be triclinic, with the cell parameters 19.58, 7.98, 8.56 A, 89.77, 89.62 and 90.27°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead1207.200207.200
38.07%
51SbAntimonyAntimony1.26121.760153.418
28.19%
16SSulfurSulfur432.060128.240
23.56%
33AsArsenicArsenic0.7474.92255.442
10.18%
Total544.300100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1966-017
  • Twinniet

In other languages

French
Twinnite
German
IMA 1966-017 · Twinnit
Italian
Twinnite

Classification

Strunz
10th ed.

2.HC.05a

  • 2Sulfides and SulfosaltsClass
  • 2.HSulfosalts of SnS archetypeDivision
  • 2.HCWith only PbGroup
  • 2.HC.05aTwinniteSpecies
Dana
8th ed.

03.07.08.03

  • 03SulfosaltsClass
  • 03.07ø = 2Type
  • 03.07.08Sartorite GroupGroup
  • 03.07.08.03TwinniteSpecies
CIM

5.6.19

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.6Sulpharsenites etc. of Pb aloneGroup
  • 5.6.19TwinniteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1967Jambor, John Leslie (1967) New lead sulfantimonides from Madoc, Ontario. Part 1. The Canadian Mineralogist, 9 (1) 7-24
  2. 1967Jambor, John Leslie (1967) New lead sulfantimonides from Madoc, Ontario. Part 2 - mineral descriptions. The Canadian Mineralogist, 9 (2) 191-213
  3. 1968Mandarino, J.A.; Kato, A. (1968) New Mineral Names. American Mineralogist, 53 (7-8). 1421-1427
  4. 1968Jambor, John Leslie (1968) New lead sulfantimonides from Madoc, Ontario. Part 3--Syntheses, paragenesis, origin. The Canadian Mineralogist, 9 (4). 505-521
  5. 1982Jambor, John L.; Laflamme, J. H. G.; Walker, D. A. (1982) A Re-examination of the Madoc Sulfosalts, in Ontario. The Mineralogical Record, 13 (2). 93-100
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Twinnite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/twinnite-4067},
  note      = {Accessed 2026-05-11}
}