Vaterite

Ca(CO3)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vtr
Discovered
1911
Also known as
  • Vateriet
  • Vaterite-B
  • μ-Calcite

Where it forms, where it's found

37recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage

Failure to report a cleavage probably due to the mineral's physical appearance: acicular, etc.

Fracture
Irregular/Uneven · Splintery
Density
2.645 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.55 – 1.65
Surface relief
Moderate
Principal indices
nω 1.55 · nε 1.65
Birefringence
0.10
Extinction
Parallel
UV response
Not known to fluoresce.
Michel-Lévy diagramhighlighted lineδ = 0.1000
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1000 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1000 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#126
Cell parameters
a = 4.13 Å · c = 8.49 Å
Z
6
Morphology

Thin fibers, spherulitic aggregates.

Comment

Wang, J.W. & Becker, U. (2009): Structure and carbonate orientation of vaterite (CaCO3). Am. Mineral. 94, 380-386. Important note: Christy (2017) actually suggests, that the correct space groups to describe the polytypes constituting the vaterite crystals are C121 (monoclinic crystal system) and P3221 (trigonal crystal system)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen315.99947.997
47.96%
20CaCalciumCalcium140.07840.078
40.04%
6CCarbonCarbon112.01112.011
12.00%
Total100.086100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Vateriet
  • Vaterite-B
  • μ-Calcite

In other languages

French
Vatérite
German
Vaterit
Spanish
Vaterita
Italian
Vaterite
Japanese
ヴァテライト
Chinese
六方方解石 · 球霰石
Russian
Ватерит · Фатерит

Classification

Strunz
10th ed.

5.AB.20

  • 5CarbonatesClass
  • 5.ACarbonates without additional anions, without H2ODivision
  • 5.ABAlkali-earth (and other M2+) carbonatesGroup
  • 5.AB.20VateriteSpecies
Dana
8th ed.

14.01.02.01

  • 14Anhydrous Normal CarbonatesClass
  • 14.01A(XO3)Type
  • 14.01.02Vaterite GroupGroup
  • 14.01.02.01VateriteSpecies
CIM

11.4.3

  • 11CarbonatesClass
  • 11.4Carbonates of CaGroup
  • 11.4.3VateriteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1911Doelter, C. (1911) Handbuch der Mineral-chemie (in 4 volumes divided into parts): 1: 113.
  2. 1911Meigen, W. (1911) Über kohlensauren Kalk. Verhandl. Ges. Deut. Naturforscher u. Ärtzte, 82, 120-124.
  3. 1916Johnston, John, Merwin, H.E., Williamson, E.D. (1916) The several forms of calcium carbonate. American Journal of Science: 41: 473-512.
  4. 1925Gibson, Wyckoff, and Merwin (1925) American Journal of Science: 10: 325 (as Vaterite-B).
  5. 1925Heide (1925) Centralblatt für Mineralogie, Geologie und Paleontologie, Stuttgart: 198.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vaterite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vaterite-4161},
  note      = {Accessed 2026-05-11}
}