Aragonite

Ca(CO3)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Arg
Discovered
1797
Also known as
  • Arragon Spar
  • Arragonischer Apatit
  • Arragonischer Kalkspath
  • +41 more

History

The mineral takes its name from a Spanish village, not the Spanish region many later writers assumed. In 1797, the German mineralogist Abraham Gottlob Werner formally named aragonite for its type locality — the village of Molina de Aragón, in what is now the province of Guadalajara. The Aragón in the village's name was repeatedly conflated by later writers with the much larger northeastern province of Aragón, hundreds of kilometres away. The misattribution is old enough that it still appears in print.

The Molina crystals are cyclic twins — clusters in which several prisms interpenetrate around a common axis — locked inside gypsum and marl of Triassic age. The form looks like a single six-sided crystal. The chemistry, CaCO₃, was already known and was supposed to crystallise as the rhombs of calcite. Werner's specimens, with the same composition, clearly did not.

The resolution — that aragonite and calcite are polymorphs, two distinct crystal forms of the same compound — was a 19th-century achievement. Aragonite is the form that is stable at high pressures. At surface conditions it is metastable: it persists for a long time but eventually converts to calcite. Older calcium-carbonate fossils, whatever their original mineralogy, are commonly found as calcite for this reason.

Industrial & practical applications

Aragonite is not a major industrial commodity. The world's bulk supply of calcium carbonateCaCO₃ — comes from limestone and chalk. Both are made of the other common form, calcite. Aragonite has no separate market at that scale. Its modern significance is biological and scientific.

The mineral is the carbonate that life prefers. Pearls are normally aragonite. The same mineral forms the shells of nearly all molluscs and the calcareous endoskeletons of warm- and cold-water corals. It is also an important component of the shells and tests — the hard outer skeletons — of many other marine invertebrates.

In reef aquaria, hobbyist tanks that recreate coral-reef conditions, aragonite is considered essential. It provides the materials that reef life needs to build its shells and skeletons. It also keeps the water's pH close to its natural level. That stability prevents the dissolution of the animals' own biogenic — biologically produced — calcium carbonate.

Beyond aquaria, aragonite has been tested for the removal of dissolved heavy metals — zinc, cobalt, and lead — from contaminated wastewater. The use sits at the research stage rather than routine industrial deployment.

Where it forms, where it's found

Geological setting

As speleothems in limestone caves; as pisolites, sinters and massive lamellar deposits at geysers and hot springs; as seafloor oolites; with siderite in iron deposits; with calcite and dolomite and other magnesium minerals in altered serpentinites, dunites and peridotites; and as a replacement mineral in various rock types and ore deposits, formed from low-temperature and pressure aqueous solutions.

Type locality
Gallo river
  1. Molina de Aragón
  2. Guadalajara
  3. Castile-La Mancha
  4. Spain

40.8503°, -1.9056°

3,163recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous to resinous.
Transparency
Transparent · Translucent
Colour
Colorless to white or grey · often stained various hues by impurities · such as blue · green · red or violet · colourless in transmitted light.
Streak
Uncolored/white.
Tenacity
brittle
Cleavage
Distinct/Good

On (010) distinct; On (110) and (011) very indistinct.

Fracture
Sub-Conchoidal
Density
2.947 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 18 – 19° · 2V calc = 16 – 18°
Refractive index
1.529 – 1.686
Surface relief
Moderate
Principal indices
nα 1.529 – 1.53 · nβ 1.68 – 1.682 · nγ 1.685 – 1.686
Dispersion
weak
Extinction
X = c; Y = a; Z = b.
Luminescence
Fluoresces pale rose, yellow, bluish, often with greenish phosphorescence, under LW, yellowish in SW.
UV response
Pale rose, yellow, white or bluish, with greenish or white phosphorescence (LW UV); yellowish (SW UV).
Michel-Lévy diagramhighlighted lineδ = 0.1560
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1560 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1560 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 4.9611(4) Å · b = 7.9672(6) Å · c = 5.7407(4) Å
Ratio a:b:c
1 : 1.606 : 1.157
Z
4
Morphology

Short to long prismatic [100], sometimes flattened (010); acicular, often with steep pyramidal or domed terminations; or tabular (001); also stalactic, columnar, in stellate or radiating aggregates, and fibrous crusts of tiny acicular crystals.

Twinning

Single crystals are typically twinned cyclically on (110) producing pseudo-hexagonal aggregates of contact and penetration twins. Polysynthetic twinning produces lamellae or fine striations parallel to [100].

Epitaxy

Mutual orientation in certain calcite pseudomorphs after aragonite. Also in aragonite pseudomorphs after gypsum, with aragonite (010)[001] parallel to the gypsum (010)[001].

Comment

Non-standard space-group setting Pmcn. Pseudohexagonal.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen315.99947.997
47.96%
20CaCalciumCalcium140.07840.078
40.04%
6CCarbonCarbon112.01112.011
12.00%
Total100.086100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Sr
  • Pb
  • Zn

Synonyms

  • Arragon Spar
  • Arragonischer Apatit
  • Arragonischer Kalkspath
  • Arragonit
  • Arragonita
  • Arragonite
  • Brudelstein
  • Carls-Erbsen
  • Carlsbader Erbsen
  • Carlsbader Pisolith
  • Chimborazit
  • Chimborazita
  • Chimborazite
  • Conchit
  • Conchita
  • Conchite
  • Excentrischer Kalkstein
  • Globuli tophacei
  • Hrachovec
  • Iglit
  • Iglita
  • Iglite
  • Igloit
  • Igloita
  • Igloite
  • Ktypéit
  • Ktypéita
  • Ktypéite
  • Marmoreus ramulosus
  • Nadelstein
  • Oserskit
  • Oserskita
  • Oserskite
  • Pisa Carolina
  • Prismatisches Kalkhaloid
  • Schallenkalk
  • Spathum prismaticum in igne lucem spargens
  • Sprudelstein
  • Stillatitius lapis
  • Vřídlovec
  • Walstein
  • Winnieit
  • Winnieita
  • Winnieite

In other languages

French
aragonite
German
Aragonit · Aragonitgruppe · Nicholsonit
Spanish
aragonita · aragonito
Italian
aragonite
Portuguese
aragonita
Japanese
アラレ石
Chinese
文石 · 霰石
Simplified Chinese
霰石
Russian
арагонит
Arabic
أراجونيت

Classification

Strunz
10th ed.

5.AB.15

  • 5CarbonatesClass
  • 5.ACarbonates without additional anions, without H2ODivision
  • 5.ABAlkali-earth (and other M2+) carbonatesGroup
  • 5.AB.15AragoniteSpecies
CIM

11.4.2

  • 11CarbonatesClass
  • 11.4Carbonates of CaGroup
  • 11.4.2AragoniteSpecies

Group, growth & confusion

In the same group
3 members
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1754Torrubia, José (1754) El Aparato para la Historia Natural Española..
  2. 1767Davila, M. (1767) Catalogue syst. et raisonné des curiosités de la nature et de l’art qui composent de cabinet de M. Davila. 3 volumes, Paris: 2: 50, 52.
  3. 1768Linnaeus (1768) Systema Naturae of Linnaeus: 183 (as Stalactites Flos ferri; Marmoreus ramulosus).
  4. 1788Klaproth (1788) Bergmaaennusches Journal, Freiberg (Neues Bergmannische Journal): 1: 299.
  5. 1788Klaproth (1788) Crell's Chemical Journal, London: 1: 387 (as carbonate of lime).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Aragonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/aragonite-307},
  note      = {Accessed 2026-05-11}
}