Zdenĕkite

NaPbCu5(AsO4)4Cl · 5H2O
IMA status
  • Approved
IMA symbol
Zde
IMA approved
1992
Also known as
  • IMA1992-037
  • Zdenĕkiet

Where it forms, where it's found

Type locality
Cap Garonne Mine
  1. Le Pradet
  2. Toulon
  3. Var
  4. Provence-Alpes-Côte d'Azur
  5. France

43.0814°, 6.0322°

6recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Translucent
Colour
Intense blue
Streak
Light blue

Optical

Optical type
Uniaxial (-)
Refractive index
1.71 – 1.77
Surface relief
High
Principal indices
nω 1.77 · nε 1.71
Michel-Lévy diagramhighlighted lineδ = 0.0600
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]600 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation600 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 10.023 Å · b = 19.55 Å · c = 10.023 Å
Cell angles
β = 90.02 °
Ratio a:b:c
1 : 1.951 : 1.000
Unit cell volume
1964 ų
Z
4
Morphology

Thin pseudotetragonal plates.

Twinning

Several twin laws appear to exist.

Comment

Space group P21/n. Pseudo-tetragonal metrics.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2115.999335.979
27.34%
29CuCopperCopper563.546317.730
25.85%
33AsArsenicArsenic474.922299.688
24.38%
82PbLeadLead1207.200207.200
16.86%
17ClChlorineChlorine135.45035.450
2.88%
11NaSodiumSodium122.99022.990
1.87%
1HHydrogenHydrogen101.00810.080
0.82%
Total1229.117100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1992-037
  • Zdenĕkiet

In other languages

German
IMA 1992-037 · Zdeněkit
Spanish
Zdenĕkita
Italian
Zdeněkite
Chinese
水氯砷钠铅铜石

Classification

Strunz
10th ed.

8.DG.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DGWith large and medium-sized cations, (OH, etc.):RO4< 0.5:1Group
  • 8.DG.05ZdenĕkiteSpecies
Dana
8th ed.

42.09.04.03

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.09(AB)7(XO4)4Zq·xH2OType
  • 42.09.04— unnamed intermediate level —Group
  • 42.09.04.03ZdenĕkiteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1995Chiappero, Pierre-Jacques, Sarp, Halil (1995) Zdenekite, NaPbCu5(AsO4)4Cl · 5H2O, a new mineral from the Cap Garonne mine, Var, France. European Journal of Mineralogy, 7 (3) 553-557 doi:10.1127/ejm/7/3/0553 DOI: 10.1127/ejm/7/3/0553
  2. 1996Mandarino, Joseph A. (1996) Abstracts of New Mineral Descriptions. The Mineralogical Record, 27 (5) 393-395
  3. 1996Jambor, John L., Pertsev, Nikolai N., Roberts, Andrew C. (1996) New mineral names. American Mineralogist, 81. 249-254
  4. 2003Zubkova, N. V., Pushcharovsky, D. Yu., Sarp, H., Teat, S. J., MacLean, E. J. (2003) Crystal structure of zdenekite NaPbCu5(AsO4)4Cl · 5H2O. Crystallography Reports, 48 (6) 939-943 doi:10.1134/1.1627435DOI: 10.1134/1.1627435
  5. 2005(2005) Zdenĕkite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zdenĕkite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zdenekite-7384},
  note      = {Accessed 2026-05-11}
}